In:
RSC Advances, Royal Society of Chemistry (RSC), Vol. 13, No. 36 ( 2023), p. 25552-25560
Abstract:
Bismuth is a promising anode material for sodium-ion batteries (SIBs) due to its high capacity and suitable working potential. However, the large volume change during alloying/dealloying would lead to poor cycling performance. Herein, we have constructed a 3D hierarchical structure assembled by bismuth nanosheets, addressing the challenges of fast kinetics, and providing efficient stress and strain relief room. The uniform bismuth nanosheets are prepared via a molten salt-assisted aluminum thermal reduction method. Compared with the commercial bismuth powder, the bismuth nanosheets present a larger specific surface area and interlayer spacing, which is beneficial for sodium ion insertion and release. As a result, the bismuth nanosheet anode presents excellent sodium storage properties with an ultralong cycle life of 6500 cycles at a high current density of 10 A g −1 , and an excellent capacity retention of 87% at an ultrahigh current rate of 30 A g −1 . Moreover, the full SIBs that paired with the Na 3 V 2 (PO 4 ) 3 /rGO cathode exhibited excellent performance. This work not only presents a novel strategy for preparing bismuth nanosheets with significantly increased interlayer spacing but also offers a straightforward synthesis method utilizing low-cost precursors. Furthermore, the outstanding performance demonstrated by these nanosheets indicates their potential for various practical applications.
Type of Medium:
Online Resource
ISSN:
2046-2069
Language:
English
Publisher:
Royal Society of Chemistry (RSC)
Publication Date:
2023
detail.hit.zdb_id:
2623224-8
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