In:
Acta Crystallographica Section C Crystal Structure Communications, International Union of Crystallography (IUCr), Vol. 69, No. 9 ( 2013-09-15), p. 1002-1005
Kurzfassung:
The structure of the photoluminescent compound hexaaquadichloridoneodymium(III) chloride has been redetermined from single-crystal X-ray diffraction data at 100 K, with the aim of providing an accurate structural model for the bulk crystalline material. The crystal structure may be described as a network of [NdCl 2 (H 2 O) 6 ] + cations with distorted square-antiprism geometry around the Nd III centre. The Nd III cation and the nonbonded Cl − anion are both located on twofold symmetry axes. The crystal packing consists of three different neodymium pairs linked by a three-dimensional network of O—H...Cl intermolecular interactions. The pair distribution function (PDF) calculated from the experimentally determined structure is used for the discussion of the local structure.
Materialart:
Online-Ressource
ISSN:
0108-2701
DOI:
10.1107/S0108270113021367
DOI:
10.1107/S0108270113021367/lg3118sup1.cif
DOI:
10.1107/S0108270113021367/lg3118Isup2.hkl
Sprache:
Unbekannt
Verlag:
International Union of Crystallography (IUCr)
Publikationsdatum:
2013
ZDB Id:
2025703-X
SSG:
13
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