In:
Polymer International, Wiley, Vol. 52, No. 9 ( 2003-09), p. 1423-1427
Abstract:
Atom transfer radical polymerization (ATRP) of ( R )‐2‐methacryloyloxy‐2′‐methoxy‐1,1′‐binaphthalene (( R )‐MAMBN) mediated by different amine ligands, copper(I) chloride and ethyl 2‐bromopropionate in different solvents, and reverse ATRP of ( R )‐MAMBN were studied. It was shown that optically active polymers were obtained, with poor control of the molecular weights, and low polydispersities. Specific rotation of the polymers increased with increasing molecular weights. By comparison with ( R )‐MAMBN, poly(( R )‐MAMBN)s exhibits higher specific rotation and a positive Cotton effect. Copyright © 2003 Society of Chemical Industry
Type of Medium:
Online Resource
ISSN:
0959-8103
,
1097-0126
Language:
English
Publisher:
Wiley
Publication Date:
2003
detail.hit.zdb_id:
2004753-8
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