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  • 1
    Online Resource
    Online Resource
    Wiley ; 2022
    In:  Sedimentology Vol. 69, No. 2 ( 2022-02), p. 845-863
    In: Sedimentology, Wiley, Vol. 69, No. 2 ( 2022-02), p. 845-863
    Abstract: End‐member modelling analysis (EMMA) is a statistical approach to unmixing multimodal grain‐size distributions to identify and quantify processes of sediment generation, transport and deposition. While the different computational implementations have been extensively benchmarked and show similarly high reliability characteristics, there is a series of unknowns regarding the applicability, quality and limitations of the method from a practical point of view. This study explores these important unknowns using both empirical and synthetic samples along with Monte Carlo tests. Under ideal conditions (all available samples, randomly mixed components, 116 grain‐size classes), EMMA is able to model the grain‐size distributions of input end‐members (loadings) with R 2 between 0.63 and 0.98 and their relative contributions to each sample (scores) with R 2 between 0.71 and 0.81, thus setting the baseline for model quality. Inappropriate model parameter settings cause severe drops in R 2 . EMMA is able to detect an end‐member even if it is present in only one sample or when it contributes less than 10 vol.‐%. With 20 to 40 samples or more, stable, high quality model results are possible. With 15 or more grain‐size classes, model results also reach such stable high reproducibility levels. EMMA can depict originally multimodal end‐members ( R 2 between 0.78 and 0.99). End‐members with identical relative grain‐size distribution shape can overlap significantly without causing quality drops; R 2 of identical distributions are invariantly high until mode positions are less than three grain‐size classes apart from each other. Gradually widening end‐member distributions do not affect the results significantly. However, shifting mode positions have a severe impact. Post‐depositional mixing causes drastic deviations of the modelled scores, whereas the loadings are virtually unaffected. In light of these tests, EMMA is a reliable, mostly unbiased tool to identify and quantify sediment generation/transport/deposition regimes from mixed sediment deposits, given that it is used in a geoscientifically meaningful context.
    Type of Medium: Online Resource
    ISSN: 0037-0746 , 1365-3091
    URL: Issue
    RVK:
    Language: English
    Publisher: Wiley
    Publication Date: 2022
    detail.hit.zdb_id: 2020955-1
    detail.hit.zdb_id: 206889-8
    SSG: 13
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  • 2
    Online Resource
    Online Resource
    Copernicus GmbH ; 2019
    In:  E&G Quaternary Science Journal Vol. 68, No. 1 ( 2019-05-16), p. 29-46
    In: E&G Quaternary Science Journal, Copernicus GmbH, Vol. 68, No. 1 ( 2019-05-16), p. 29-46
    Abstract: Abstract. The analysis of grain-size distributions has a long tradition in Quaternary Science and disciplines studying Earth surface and subsurface deposits. The decomposition of multi-modal grain-size distributions into inherent subpopulations, commonly termed end-member modelling analysis (EMMA), is increasingly recognised as a tool to infer the underlying sediment sources, transport and (post-)depositional processes. Most of the existing deterministic EMMA approaches are only able to deliver one out of many possible solutions, thereby shortcutting uncertainty in model parameters. Here, we provide user-friendly computational protocols that support deterministic as well as robust (i.e. explicitly accounting for incomplete knowledge about input parameters in a probabilistic approach) EMMA, in the free and open software framework of R. In addition, and going beyond previous validation tests, we compare the performance of available grain-size EMMA algorithms using four real-world sediment types, covering a wide range of grain-size distribution shapes (alluvial fan, dune, loess and floodplain deposits). These were randomly mixed in the lab to produce a synthetic data set. Across all algorithms, the original data set was modelled with mean R2 values of 0.868 to 0.995 and mean absolute deviation (MAD) values of 0.06 % vol to 0.34 % vol. The original grain-size distribution shapes were modelled as end-member loadings with mean R2 values of 0.89 to 0.99 and MAD of 0.04 % vol to 0.17 % vol. End-member scores reproduced the original mixing ratios in the synthetic data set with mean R2 values of 0.68 to 0.93 and MAD of 0.1 % vol to 1.6 % vol. Depending on the validation criteria, all models provided reliable estimates of the input data, and each of the models exhibits individual strengths and weaknesses. Only robust EMMA allowed uncertainties of the end-members to be objectively estimated and expert knowledge to be included in the end-member definition. Yet, end-member interpretation should carefully consider the geological and sedimentological meaningfulness in terms of sediment sources, transport and deposition as well as post-depositional alteration of grain sizes. EMMA might also be powerful in other geoscientific contexts where the goal is to unmix sources and processes from compositional data sets.
    Type of Medium: Online Resource
    ISSN: 2199-9090
    Language: English
    Publisher: Copernicus GmbH
    Publication Date: 2019
    detail.hit.zdb_id: 2572732-1
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  • 3
    Online Resource
    Online Resource
    Schweizerbart ; 2011
    In:  Zeitschrift für Geomorphologie, Supplementary Issues Vol. 55, No. 3 ( 2011-06-01), p. 49-75
    In: Zeitschrift für Geomorphologie, Supplementary Issues, Schweizerbart, Vol. 55, No. 3 ( 2011-06-01), p. 49-75
    Type of Medium: Online Resource
    ISSN: 1864-1687
    Uniform Title: Ambiguities of relative age indicators on abandoned surfaces of arid environments
    Language: English , English
    Publisher: Schweizerbart
    Publication Date: 2011
    SSG: 13
    SSG: 14
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  • 4
    Online Resource
    Online Resource
    Cambridge University Press (CUP) ; 2016
    In:  Quaternary Research Vol. 85, No. 1 ( 2016-01), p. 4-16
    In: Quaternary Research, Cambridge University Press (CUP), Vol. 85, No. 1 ( 2016-01), p. 4-16
    Abstract: Reconstructing the evolution of arid landscapes is challenged by limited availability of appropriate environmental archives. A widespread surface feature — stone pavement — traps aeolian fines and forms a special accretionary archive. Seven stone pavement-covered sections on basalt flows in the eastern Mojave Desert are condensed into a composite section, comprising five sedimentological units supported by an OSL-based chronology. Three of the units are of accretionary nature and each is covered by a stone pavement. They were deposited 〉 50.9–36.6 ka, 〈 36.6–14.2 ka and 〈 14.2 ka, and they are intimately coupled with the history of nearby Lake Mojave, which advances the current understanding of regional aeolian activity. End-member modeling analysis of grain-size distributions yielded seven sediment transport regimes. The accretionary system operates in two modes: A) episodic formation of a stone pavement by lateral processes once a vesicular horizon has formed on a barren surface; and B) accretion of dust and eventual burial of the clast layer. These findings improve current concepts about stone pavement evolution and their environmental proxy function in arid landscapes. Stone pavement-covered accretionary deposits are a new key archive that allows quantifying the relative importance of dust accretion, slope processes, soil formation and vegetation cover.
    Type of Medium: Online Resource
    ISSN: 0033-5894 , 1096-0287
    RVK:
    Language: English
    Publisher: Cambridge University Press (CUP)
    Publication Date: 2016
    detail.hit.zdb_id: 1471589-2
    detail.hit.zdb_id: 205711-6
    SSG: 13
    SSG: 14
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  • 5
    In: PLOS ONE, Public Library of Science (PLoS), Vol. 14, No. 9 ( 2019-9-16), p. e0222011-
    Type of Medium: Online Resource
    ISSN: 1932-6203
    Language: English
    Publisher: Public Library of Science (PLoS)
    Publication Date: 2019
    detail.hit.zdb_id: 2267670-3
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  • 6
    Online Resource
    Online Resource
    Informa UK Limited ; 2005
    In:  International Journal of Environmental Analytical Chemistry Vol. 85, No. 15 ( 2005-12-15), p. 1141-1152
    In: International Journal of Environmental Analytical Chemistry, Informa UK Limited, Vol. 85, No. 15 ( 2005-12-15), p. 1141-1152
    Type of Medium: Online Resource
    ISSN: 0306-7319 , 1029-0397
    RVK:
    Language: English
    Publisher: Informa UK Limited
    Publication Date: 2005
    detail.hit.zdb_id: 2038320-4
    SSG: 13
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  • 7
    In: Biogeosciences, Copernicus GmbH, Vol. 14, No. 5 ( 2017-03-15), p. 1261-1283
    Abstract: Abstract. The composition of perennially frozen deposits holds information on the palaeo-environment during and following deposition. In this study, we investigate late Pleistocene permafrost at the western coast of the Buor Khaya Peninsula in the south-central Laptev Sea (Siberia), namely the prominent eastern Siberian Yedoma Ice Complex (IC). Two Yedoma IC exposures and one drill core were studied for cryolithological (i.e. ice and sediment features), geochemical, and geochronological parameters. Borehole temperatures were measured for 3 years to capture the current thermal state of permafrost. The studied sequences were composed of ice-oversaturated silts and fine-grained sands with considerable amounts of organic matter (0.2 to 24 wt %). Syngenetic ice wedges intersect the frozen deposits. The deposition of the Yedoma IC, as revealed by radiocarbon dates of sedimentary organic matter, took place between 54.1 and 30.1 kyr BP. Continued Yedoma IC deposition until about 14.7 kyr BP is shown by dates from organic matter preserved in ice-wedge ice. For the lowermost and oldest Yedoma IC part, infrared-stimulated luminescence dates on feldspar show deposition ages between 51.1 ± 4.9 and 44.2 ± 3.6 kyr BP. End-member modelling was applied to grain-size-distribution data to determined sedimentation processes during Yedoma IC formation. Three to five robust end-members were detected within Yedoma IC deposits, which we interpret as different modes of primary and reworked unconfined alluvial slope and fan deposition as well as of localized eolian and fluvial sediment, which is overprinted by in situ frost weathering. The cryolithological inventory of the Yedoma IC preserved on the Buor Khaya Peninsula is closely related to the results of other IC studies, for example, to the west on the Bykovsky Peninsula, where formation time (mainly during the late Pleistocene marine isotope stages (MIS) 3 interstadial) and formation conditions were similar. Local freezing conditions on Buor Khaya, however, differed and created solute-enriched (salty) and isotopically light pore water pointing to a small talik layer and thaw-bulb freezing after deposition. Due to intense coastal erosion, the biogeochemical signature of the studied Yedoma IC represents the terrestrial end-member, and is closely related to organic matter currently being deposited in the marine realm of the Laptev Sea shelf.
    Type of Medium: Online Resource
    ISSN: 1726-4189
    Language: English
    Publisher: Copernicus GmbH
    Publication Date: 2017
    detail.hit.zdb_id: 2158181-2
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  • 8
    In: Climate of the Past, Copernicus GmbH, Vol. 16, No. 2 ( 2020-04-30), p. 799-818
    Abstract: Abstract. Landscapes in high northern latitudes are assumed to be highly sensitive to future global change, but the rates and long-term trajectories of changes are rather uncertain. In the boreal zone, fires are an important factor in climate–vegetation interactions and biogeochemical cycles. Fire regimes are characterized by small, frequent, low-intensity fires within summergreen boreal forests dominated by larch, whereas evergreen boreal forests dominated by spruce and pine burn large areas less frequently but at higher intensities. Here, we explore the potential of the monosaccharide anhydrides (MA) levoglucosan, mannosan and galactosan to serve as proxies of low-intensity biomass burning in glacial-to-interglacial lake sediments from the high northern latitudes. We use sediments from Lake El'gygytgyn (cores PG 1351 and ICDP 5011-1), located in the far north-east of Russia, and study glacial and interglacial samples of the last 430 kyr (marine isotope stages 5e, 6, 7e, 8, 11c and 12) that had different climate and biome configurations. Combined with pollen and non-pollen palynomorph records from the same samples, we assess how far the modern relationships between fire, climate and vegetation persisted during the past, on orbital to centennial timescales. We find that MAs attached to particulates were well-preserved in up to 430 kyr old sediments with higher influxes from low-intensity biomass burning in interglacials compared to glacials. MA influxes significantly increase when summergreen boreal forest spreads closer to the lake, whereas they decrease when tundra-steppe environments and, especially, Sphagnum peatlands spread. This suggests that low-temperature fires are a typical characteristic of Siberian larch forests also on long timescales. The results also suggest that low-intensity fires would be reduced by vegetation shifts towards very dry environments due to reduced biomass availability, as well as by shifts towards peatlands, which limits fuel dryness. In addition, we observed very low MA ratios, which we interpret as high contributions of galactosan and mannosan from biomass sources other than those currently monitored, such as the moss–lichen mats in the understorey of the summergreen boreal forest. Overall, sedimentary MAs can provide a powerful proxy for fire regime reconstructions and extend our knowledge of long-term natural fire–climate–vegetation feedbacks in the high northern latitudes.
    Type of Medium: Online Resource
    ISSN: 1814-9332
    Language: English
    Publisher: Copernicus GmbH
    Publication Date: 2020
    detail.hit.zdb_id: 2217985-9
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  • 9
    In: Ecology and Evolution, Wiley, Vol. 10, No. 2 ( 2020-01), p. 962-979
    Abstract: Shrub encroachment has far‐reaching ecological and economic consequences in many ecosystems worldwide. Yet, compositional changes associated with shrub encroachment are often overlooked despite having important effects on ecosystem functioning. We document the compositional change and potential drivers for a northern Namibian Combretum woodland transitioning into a Terminalia shrubland. We use a multiproxy record (pollen, sedimentary ancient DNA, biomarkers, compound‐specific carbon (δ 13 C) and deuterium (δD) isotopes, bulk carbon isotopes (δ 13 Corg), grain size, geochemical properties) from Lake Otjikoto at high taxonomical and temporal resolution. We provide evidence that state changes in semiarid environments may occur on a scale of one century and that transitions between stable states can span around 80 years and are characterized by a unique vegetation composition. We demonstrate that the current grass/woody ratio is exceptional for the last 170 years, as supported by n ‐alkane distributions and the δ 13 C and δ 13 Corg records. Comparing vegetation records to environmental proxy data and census data, we infer a complex network of global and local drivers of vegetation change. While our δD record suggests physiological adaptations of woody species to higher atmospheric p CO 2 concentration and drought, our vegetation records reflect the impact of broad‐scale logging for the mining industry, and the macrocharcoal record suggests a decrease in fire activity associated with the intensification of farming. Impact of selective grazing is reflected by changes in abundance and taxonomical composition of grasses and by an increase of nonpalatable and trampling‐resistant taxa. In addition, grain‐size and spore records suggest changes in the erodibility of soils because of reduced grass cover. Synthesis. We conclude that transitions to an encroached savanna state are supported by gradual environmental changes induced by management strategies, which affected the resilience of savanna ecosystems. In addition, feedback mechanisms that reflect the interplay between management legacies and climate change maintain the encroached state.
    Type of Medium: Online Resource
    ISSN: 2045-7758 , 2045-7758
    URL: Issue
    Language: English
    Publisher: Wiley
    Publication Date: 2020
    detail.hit.zdb_id: 2635675-2
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  • 10
    In: Nanoscale, Royal Society of Chemistry (RSC), Vol. 13, No. 2 ( 2021), p. 930-938
    Type of Medium: Online Resource
    ISSN: 2040-3364 , 2040-3372
    Language: English
    Publisher: Royal Society of Chemistry (RSC)
    Publication Date: 2021
    detail.hit.zdb_id: 2515664-0
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