In:
CHIMIA, Swiss Chemical Society, Vol. 50, No. 12 ( 1996-12-18), p. 618-
Abstract:
The rate constants and activation parameters for solvent exchange for a series of RhIII and IrIII complexes of the form [M(H2O)6]3+ (M = Rh or Ir) and [Cp*M(S)3] 2+ (M = Rh or Ir, and S = H2O, MeCN, or Me2SO) have been determined by NMR spectroscopy as a function of free-solvent concentration, temperature, and pressure, and the mechanisms for the respective exchange processes have been inferred.
Type of Medium:
Online Resource
ISSN:
2673-2424
,
0009-4293
DOI:
10.2533/chimia.1996.618
Language:
Unknown
Publisher:
Swiss Chemical Society
Publication Date:
1996
detail.hit.zdb_id:
2179192-2
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