In:
Journal of Porphyrins and Phthalocyanines, World Scientific Pub Co Pte Ltd, Vol. 07, No. 08 ( 2003-08), p. 572-578
Abstract:
29H,31H-(2,4-di-t-amylphenoxy)phthalocyanine, Zn (II) tetra-4-(2,4-di-t-amylphenoxy) phthalocyanine and Zn (II) tris-(2,4-di-t-amylphenoxy)-[4-(4-mercapto-phenyliminomethyl)- phenoxy]phthalocyanine were synthesized and their molecular structures were confirmed by LC-MS, 1 H NMR, FT-IR and UV-vis spectra. Spin coated layers of these phthalocyanines have been used as optochemically interactive materials for volatile organic compounds detection in the UV-vis spectral range. The results show a good sensitivity and selectivity depending on both the metal and the peripheral substituents. Optic al sensitivity towards tert-butylamine, diethylamine, dibutylamine, 2-butanone and acetic acid has been monitored.
Type of Medium:
Online Resource
ISSN:
1088-4246
,
1099-1409
DOI:
10.1142/S1088424603000720
Language:
English
Publisher:
World Scientific Pub Co Pte Ltd
Publication Date:
2003
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