In:
Zeitschrift für anorganische und allgemeine Chemie, Wiley, Vol. 640, No. 1 ( 2014-01), p. 159-167
Abstract:
Four complexes with supramolecular architectures, namely, MZCA · 3H 2 O ( 1 ), [Zn(H 2 O) 6 ] 2+ · [MZCA] 2 · [H 2 O] 6 ( 2 ), [Mn(MZCA) 2 (H 2 O) 4 ] · 2H 2 O ( 3 ), and [Ni(MZCA) 2 (H 2 O) 4 ] · 2H 2 O ( 4 ) [MZCA = 3‐(carboxymethyl)‐2, 7‐dimethyl‐3H‐benzo[d]imidazole‐5‐carboxylic acid] , were synthesized and characterized by elemental analysis, IR spectroscopy, and single‐crystal X‐ray diffraction. Complexes 1 and 2 display a remarkable 3D network with 1D hydrophilic channels. Complexes 3 and 4 are isostructural and exhibit a 3D structure encapsulating 1D 24‐membered ring microporous channels. The UV/Vis and fluorescent spectra were measured to characterize complexes 1 – 4 . The thermal stability of complexes 2 – 4 were also examined.
Type of Medium:
Online Resource
ISSN:
0044-2313
,
1521-3749
DOI:
10.1002/zaac.201300154
Language:
English
Publisher:
Wiley
Publication Date:
2014
detail.hit.zdb_id:
201094-X
detail.hit.zdb_id:
1481139-X
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