In:
Angewandte Chemie, Wiley, Vol. 133, No. 17 ( 2021-04-19), p. 9376-9381
Abstract:
Access to dithiophene‐fused oxadiborepins and the first azadiborepins attained via a modular synthesis route are presented. The new compounds emit intense blue light, some of which demonstrate fluorescence quantum yields close to unity. Cyclic voltammetry (CV) revealed electrochemically reversible one‐electron reduction processes. The weak aromatic character of the novel 1,2,7‐azadiborepin ring is demonstrated with in‐depth theoretical investigations using nucleus‐independent chemical shift (NICS) scans and anisotropy of the induced current density (ACID) calculations.
Type of Medium:
Online Resource
ISSN:
0044-8249
,
1521-3757
DOI:
10.1002/ange.v133.17
DOI:
10.1002/ange.202100295
Language:
English
Publisher:
Wiley
Publication Date:
2021
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505872-7
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1479266-7
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