In:
Dalton Transactions, Royal Society of Chemistry (RSC), Vol. 51, No. 10 ( 2022), p. 3778-3806
Abstract:
Over the past decade, the reactivity of 2-phosphaethynolate (OCP − ), a heavier analogue of the cyanate anion, has been the subject of momentous interest in the field of modern organometallic chemistry. It is used as a precursor to novel phosphorus-containing heterocycles and as a ligand in decarbonylative processes, serving as a synthetic equivalent of a phosphinidene derivative. This perspective aims to describe advances in the reactivities of phosphaethynolate and arsaethynolate anions (OCE − ; E = P, As) with main-group element, transition metal, and f-block metal scaffolds. Further, the unique structures and bonding properties are discussed based on spectroscopic and theoretical studies.
Type of Medium:
Online Resource
ISSN:
1477-9226
,
1477-9234
Language:
English
Publisher:
Royal Society of Chemistry (RSC)
Publication Date:
2022
detail.hit.zdb_id:
1472887-4
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