In:
Zeitschrift für Naturforschung B, Walter de Gruyter GmbH, Vol. 73, No. 3-4 ( 2018-4-25), p. 203-210
Abstract:
A trinuclear Co(II) complex, [{CoL(C 4 H 9 OH)} 2 -(OAc) 2 Co]·C 3 H 7 NO, was synthesized by the reaction of a Salamo-type chelating ligand (H 2 L=4,42′-dinitro-2,2′-[1,2-ethylenedioxybis(nitrilomethylidyne)]diphenol) with cobalt(II) acetate tetrahydrate in n -butanol, and characterized by elemental analyses, X-ray crystallography, FT-IR and UV/Vis spectra. In the Co(II) complex, there are two ligand L 2− units, two μ 2 -acetate ions, two coordinated n -butanol molecules and one non-coordinated N , N -dimethylformamide molecule. The Co(II) atoms in the structure of the Co(II) complex adopt slightly distorted octahedra geometries. Furthermore, through intermolecular C–H···O, O–H···O and C–H···π interactions, infinite layer-like, plane-like and 3D supramolecular structures are constructed. The fluorescence and electrochemical properties of the Co(II) complex have also been investigated.
Type of Medium:
Online Resource
ISSN:
1865-7117
,
0932-0776
DOI:
10.1515/znb-2017-0191
Language:
English
Publisher:
Walter de Gruyter GmbH
Publication Date:
2018
detail.hit.zdb_id:
2078109-X
detail.hit.zdb_id:
124635-5
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