In:
IUCrData, International Union of Crystallography (IUCr), Vol. 7, No. 7 ( 2022-07-28)
Abstract:
The title compound, [Ir(C 8 H 12 )(C 6 H 11 N 3 )(C 18 H 33 P)]BF 4 ·CH 2 Cl 2 , a triazole-based N-heterocyclic carbene iridium(I) cationic complex with a tetrafluoridoborate counter-anion, crystallizes with one dichloromethane solvent molecule per formula unit. The Ir I atom of the cationic complex has a distorted square-planar coordination environment, defined by a bidentate cycloocta-1,5-diene (COD) ligand, an N-heterocyclic carbene, and a tricyclohexylphosphane ligand. The complex crystallizes in a C -centered monoclinic unit cell and has an unusually high number of eight formula units.
Type of Medium:
Online Resource
ISSN:
2414-3146
DOI:
10.1107/S241431462200685X
DOI:
10.1107/S241431462200685X/wm4168sup1.cif
DOI:
10.1107/S241431462200685X/wm4168Isup2.hkl
Language:
Unknown
Publisher:
International Union of Crystallography (IUCr)
Publication Date:
2022
detail.hit.zdb_id:
2847714-5
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