In:
Journal of Mass Spectrometry, Wiley, Vol. 36, No. 5 ( 2001-05), p. 529-537
Abstract:
Electrospray ionization mass spectrometry (ESIMS) was used to characterize a series of new ruthenium(II) complexes with several nitrogen heterocycles and a common ligand: the crown thioether 1,4,7‐trithiacyclononane, [9]aneS 3 . ESIMS allows the easy identification of the [Ru II Cl([9]aneS 3 )Y]X complexes, where Y is a bidentate nitrogen heterocycle and X is Cl − or PF 6 − , through the formation of two diagnostic ions by fragmentation of the common ligand [9]aneS 3 . Structures for these ions and mechanisms for their gas‐phase formation are proposed based on data from product ion spectra. Copyright © 2001 John Wiley & Sons, Ltd.
Type of Medium:
Online Resource
ISSN:
1076-5174
,
1096-9888
Language:
English
Publisher:
Wiley
Publication Date:
2001
detail.hit.zdb_id:
2197367-2
detail.hit.zdb_id:
1472468-6
detail.hit.zdb_id:
7414-7
SSG:
11
SSG:
12
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