In:
Chemistry – A European Journal, Wiley, Vol. 11, No. 8 ( 2005-04-08), p. 2433-2439
Abstract:
Crystallisation of trithiocyanuric acid ( TTCA ) from various organic solvents that have hydrogen bonding capability (acetone, 2‐butanone, dimethylformamide, dimethyl sulfoxide, methanol and acetonitrile) leads to the formation of co‐crystals in which the solvent molecules are incorporated together with TTCA in the crystal structure. Structure determination by single‐crystal X‐ray diffraction reveals that these co‐crystals can be classified into different groups depending upon the topological arrangement of the TTCA molecules in the crystal structure. Thus, three different types of single‐tape arrangements of TTCA molecules and one type of double‐tape arrangement of TTCA molecules are identified. In all co‐crystals, hydrogen‐bonding interactions are formed through the involvement of NH bonds of TTCA molecules in these tapes and the other molecule in the co‐crystal. Detailed rationalisation of the structural properties of these co‐crystals is presented.
Type of Medium:
Online Resource
ISSN:
0947-6539
,
1521-3765
DOI:
10.1002/chem.200400340
Language:
English
Publisher:
Wiley
Publication Date:
2005
detail.hit.zdb_id:
1478547-X
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