In:
European Journal of Inorganic Chemistry, Wiley, Vol. 2006, No. 12 ( 2006-06), p. 2353-2356
Abstract:
The novel cationic complex [Ag 14 (C 2 t Bu) 12 ] 2+ has been synthesized by four reactions: reaction of [Ag(C 2 t Bu)] n and AgBF 4 in acetone in a 6:1 mole ratio, that of HC≡C t Bu and AgBF 4 in water in the absence of a base, treatment of [AgC 2 t Bu] n with HBF 4 in acetone or that of {[Ag 3 (C 2 t Bu) 2 ][BF 4 ]} n with [Ag(C 2 t Bu)] n in a 1:4 mole ratio. Single‐crystal X‐ray studies showed it to be a hexacapped cube of silver( I ) atoms, with twelve η 1 , μ 3 ‐C 2 t Bu ligands. (© Wiley‐VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2006)
Type of Medium:
Online Resource
ISSN:
1434-1948
,
1099-0682
DOI:
10.1002/ejic.v2006:12
DOI:
10.1002/ejic.200600128
Language:
English
Publisher:
Wiley
Publication Date:
2006
detail.hit.zdb_id:
1475009-0
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