In:
Chemical Communications, Royal Society of Chemistry (RSC), Vol. 59, No. 27 ( 2023), p. 4024-4027
Kurzfassung:
In this work, we report a low-valent Ga( i ) complex, [Ga@Bi 10 (NbMes) 2 ] 3− , with a linear Nb–Ga–Nb fragment, representing the first compound with Nb–Ga and Nb–Bi bonds. Quantum-chemical calculations reveal that the complex is an electron-precise cluster. The possible fragmentation pathway of the title cluster was studied by using electrospray ionization mass spectrometry and theoretical calculations.
Materialart:
Online-Ressource
ISSN:
1359-7345
,
1364-548X
Sprache:
Englisch
Verlag:
Royal Society of Chemistry (RSC)
Publikationsdatum:
2023
ZDB Id:
1472881-3
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