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  • 1
    Online Resource
    Online Resource
    Dordrecht :Springer Netherlands,
    Keywords: Ocean circulation-Congresses. ; Electronic books.
    Description / Table of Contents: Proceedings of the NATO Advanced Study Institute, Les Houches, France, February 11-22, 1985.
    Type of Medium: Online Resource
    Pages: 1 online resource (384 pages)
    Edition: 1st ed.
    ISBN: 9789400947689
    Series Statement: Nato Science Series C: Series ; v.190
    Language: English
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  • 2
    Online Resource
    Online Resource
    Dordrecht :Springer Netherlands,
    Keywords: Ocean circulation-Computer simulation-Congresses. ; Electronic books.
    Description / Table of Contents: Proceedings of the NATO Advanced Study Institute on Modelling the Ocean General Circulation and Geochemical Tracer Transport, Les Houches, France, February 15-26, 1988.
    Type of Medium: Online Resource
    Pages: 1 online resource (616 pages)
    Edition: 1st ed.
    ISBN: 9789400910133
    Series Statement: Nato Science Series C: Series ; v.284
    Language: English
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  • 3
    Online Resource
    Online Resource
    Berlin, Heidelberg :Springer Berlin / Heidelberg,
    Keywords: Bones-Physiology. ; Bones-Pathophysiology. ; Bones-Effect of drugs on. ; Electronic books.
    Type of Medium: Online Resource
    Pages: 1 online resource (774 pages)
    Edition: 1st ed.
    ISBN: 9783642779916
    Series Statement: Handbook of Experimental Pharmacology Series ; v.107
    DDC: 612.75
    Language: English
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  • 4
    Online Resource
    Online Resource
    San Diego :Elsevier Science & Technology,
    Keywords: Peroxides -- Analysis. ; Electronic books.
    Type of Medium: Online Resource
    Pages: 1 online resource (130 pages)
    Edition: 1st ed.
    ISBN: 9781483160191
    Language: English
    Note: Front Cover -- The Determination of Organic Peroxides -- Copyright Page -- Table of Contents -- PREFACE -- CHAPTER 1. INTRODUCTION -- 1. Lipid Peroxides -- 2 . Polymers -- 3 . Petrochemicals -- 4 . Irradiation -- 5. Miscellaneous -- References -- CHAPTER 2 . STRUCTURE AND REACTIVITY -- 1 . Classification of peroxides -- 2 . Reactivity -- References -- CHAPTER 3. IODOMETRIC METHODS -- 1 . General comments -- 2. Choice of solvent -- 3 . Reaction conditions -- 4 . Titration with thiosulphate -- References -- CHAPTER 4 . FERROUS ION METHODS -- 1 . Introduction -- 2 . Choice of reagent -- 3. Choice of solvent -- 4 . Titration with titanous ions -- 5 . Titration with dichromate ions -- 6 . Titration with mercurous ions -- References -- CHAPTER 5. FURTHER TITRIMETRIC REAGENTS -- 1 . Introduction -- 2 . Arsenious methods -- 3 . Stannous methods -- 4 . Titanous methods -- 5 . Titration with anions -- 6. Sulphides and mercaptans -- References -- CHAPTER 6 . COLORIMETRIC METHODS -- 1 . Introduction -- 2 . Ferrous ions -- 3 . Leuco base of methylene blue -- 4 . Iodine -- 5. iV,A^'-Dimethyl-/?-phenylenediamme -- 6. Other colorimetric reagents -- References -- CHAPTER 7 . POLAROGRAPHIC METHODS -- 1 . Introduction -- 2 . Electrode reaction -- 3 . Polarographic teclmiques for peroxides -- 4 . Nature and concentration of peroxide -- 5 . Solvents and supporting electrolytes -- References -- CHAPTER 8. SPECTROSCOPIC TECHNIQUES -- 1 . Introduction -- 2 . Ultraviolet and visible absorption -- 3 . Infrared absorption -- 4 . Raman spectroscopy -- References -- CHAPTER 9 . CHROMATOGRAPHIC METHODS A. COLUMN CHROMATOGRAPHY -- 1 . Introduction -- 2 . Column techniques -- 3 . Solvent medium -- 4 . Stationary phase -- 5 . Type of peroxide -- References -- CHAPTER 10 . CHROMATOGRAPHIC METHODS B. PAPER CHROMATOGRAPHY -- 1 . Introduction -- 2 . Choice of paper. , 3. Mobile phase -- 4 . General techniques -- 5 . Chemical structure -- 6 . Detection -- 7 . Class of peroxide -- References -- CHAPTER 11 . CHROMATOGRAPHIC METHODS C. THIN-LAYER CHROMATOGRAPHY -- 1 . Introduction -- 2 . Adsorbents -- 3 . Solvent systems -- 4. Detection -- 5. Techniques -- 6. Applications -- References -- CHAPTER 12. CHROMATOGRAPHIC METHODS D. GAS CHROMATOGRAPHY -- 1. Introduction -- 2. Solid support -- 3. Stationary phase -- 4. Column temperature -- 5. Functional groups -- 6. Quantitative analysis -- References -- CHAPTER 13. CHOICE OF METHOD -- 1. Introduction -- 2. Concentration of peroxide -- 3. Reactivity of peroxide -- 4. Nature of the sample -- INDEX.
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  • 5
    Online Resource
    Online Resource
    Berlin, Heidelberg :Springer Berlin / Heidelberg,
    Keywords: Electronic books.
    Type of Medium: Online Resource
    Pages: 1 online resource (480 pages)
    Edition: 1st ed.
    ISBN: 9783642676376
    Series Statement: Ecological Studies ; v.36
    Language: English
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  • 6
    Online Resource
    Online Resource
    San Diego :Elsevier Science & Technology,
    Keywords: Epoxy compounds -- Analysis. ; Electronic books.
    Type of Medium: Online Resource
    Pages: 1 online resource (88 pages)
    Edition: 1st ed.
    ISBN: 9781483150536
    Language: English
    Note: Front Cover -- The Determination of Epoxide Groups -- Copyright Page -- Table of Contents -- PREFACE -- CHAPTER 1. INTRODUCTION -- 1. General considerations -- 2. The determination of epoxide groups -- 3. Analytical methods -- References -- CHAPTER 2. METHODS INVOLVING EPOXIDE RING-OPENING BY HALOGEN ACIDS -- INTRODUCTION -- 1. Procedures considered -- 2. General comments -- 3. Interference effects -- 4. Convenience of the various procedures -- 5. Accuracy -- 6. Conclusions -- References -- CHAPTER 3. OTHER METHODS FOR EPOXIDE DETERMINATION -- INTRODUCTION -- 1. Methods considered -- 2. General comments -- References -- CHAPTER 4. CONCLUSIONS -- Chemical methods -- Physical methods -- Very sensitive methods -- Final comments -- INDEX.
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  • 7
    Online Resource
    Online Resource
    Kent :Elsevier Science & Technology,
    Keywords: Zotterman, Yngve. ; Neurophysiology -- Congresses. ; Electronic books.
    Description / Table of Contents: Physiology: Past, Present and Future documents the proceedings of a symposium in honor of Yngve Zotterman held in the Department of Physiology, Medical School, University of Bristol on 11-12 July 1979. The idea for the symposium was spurred by the knowledge that Yngve would reach the age of 80 in September 1978 and the belief that he would welcome a meeting to celebrate his great age and achievement, in the company of some of his distinguished friends and collaborators. The symposium discussed advances in several branches of physiology. These include studies on C-fiber afferents in the viscera, skin, and deeper somatic tissues; touch and pain; tactile paths in the nervous systems of mammals; jaw reflexes evoked from the cerebral cortex; thermoreception; and temperature sensitivity of humans and monkeys. Also included are papers on taste cell transduction; how the sense of taste controls appetitive and instrumental behavior; and structural changes in the excitable membrane during excitation. The book concludes with a discussion on future trends, which begins with some challenging remarks by Yngve Zotterman. These remarks are then taken up and developed by the speakers.
    Type of Medium: Online Resource
    Pages: 1 online resource (166 pages)
    Edition: 1st ed.
    ISBN: 9781483145679
    DDC: 599
    Language: English
    Note: Front Cover -- Physiology Past, Present and Future: A Symposium in Honour of Yngve Zotterman -- Copyright Page -- Table of Contents -- LIST OF PARTICIPANTS -- PREFACE -- ACKNOWLEDGEMENTS -- INTRODUCTION -- CHAPTER 1. THE SAGA OF THE 'C' FIBRES -- ABSTRACT -- KEYWORDS -- INTRODUCTION -- ELECTROPHYSIOLOGY. WAVES AND UNIT POTENTIALS -- SINGLE UNIT ANALYSIS -- VISCERAL AFFERENT C-FIBRES -- CUTANEOUS C-FIBRES -- DEEPER SOMATIC C-FIBRES -- CONCLUDING REMARKS -- REFERENCES -- CHAPTER 2. TOUCH AND PAIN-FACTS AND CONCEPTS, OLD AND NEW -- THE ORIGINS OF TACTILE NEUROPHYSIOLOCGY -- THE PRESENT STATE OF NEUROPHYSIOLOGY OF TOUCH -- THE BIOLOGICAL NOISE IN RECEPTOR DISCHARGES -- PSYCHO-NEURONAL CORRELATIONS -- EFFECTS OF ISCHEMIA IN THE SKIN SENSES -- NOCICEPTORS FROM 1936 TO 1979 -- NOCICEPTOR REGENERATION AFTER NERVE LESIONS -- INHIBITION OF PAIN INFORMATION IN THE CENTRAL NERVOUS SYSTEM -- EPILOGUE -- ACKNOWLEDGEMENTS -- REFERENCES -- CHAPTER 3. MULTIPLE TACTILE PATHS IN THE NERVOUS SYSTEM OF MAMMALS -- ABSTRACT -- KEYWORDS -- INTRODUCTION -- CLINICAL EVIDENCE -- EXPERIMENTAL EVIDENCE FROM ANIMALS -- REFERENCES -- CHAPTER 4. CEREBRAL CONTROL OF JAW REFLEXES -- ABSTRACT -- KEYWORDS -- INTRODUCTION -- ACKNOWLEDGEMENT -- REFERENCES -- CHAPTER 5. THERMORECEPTION -- ABSTRACT -- KEYWORDS -- INTRODUCTION -- STATIC COLD RECEPTION -- ACROSS-FIBER PATTERN -- LOW-TEMPERATURE RECEPTORS -- WARM RECEPTION -- TRANSDUCER MECHANISMS -- EFFECT OF CALCIUM AND EDTA -- CONCLUDING REMARKS -- REFERENCES -- CHAPTER 6. TEMPERATURE SENSITIVITY IN HUMAN AND NON-HUMAN PRIMATES -- ABSTRACT -- KEYWORDS -- ADAPTING TEMPERATURE AND DETECTABILITY -- SPATIAL SUMMATION AND DETECTABILITY -- ACKNOWLEDGEMENT -- REFERENCES -- CHAPTER 7. SELECTED REMARKS ABOUT TASTE CELL TRANSDUCTION -- ABSTRACT -- KEYWORDS -- FOREWORD -- INTRODUCTION -- STIMULUS TRANSPORT. , INITIAL BINDING ASSOCIATED WITH RECEPTOR STIMULATION -- TASTE RECEPTOR POTENTIALS -- MODELS OF TASTE CELL TRANSDUCTION -- NEURAL ACTIVITY -- SUMMARY -- Appendix -- REFERENCES -- CHAPTER 8. THE SENSE OF TASTE AND BEHAVIOR -- ABSTRACT -- KEYWORDS -- INTRODUCTION -- TASTE AND BEHAVIOR -- ACKNOWLEDGEMENT -- REFERENCES -- CHAPTER 9. STRUCTURAL CHANGES IN THE EXCITABLE MEMBRANE DURING EXCITATION -- ABSTRACT -- KEYWORDS -- INTRODUCTION -- BIREFRINGENCE CHANGE DURING EXCITATION -- THE THERMAL SPIKE -- REFERENCES -- DISCUSSION -- Introduction -- Summary -- REFERENCES.
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  • 8
    Online Resource
    Online Resource
    San Diego :Elsevier Science & Technology,
    Keywords: Carboxylic acids -- Analysis. ; Electronic books.
    Type of Medium: Online Resource
    Pages: 1 online resource (141 pages)
    Edition: 1st ed.
    ISBN: 9781483151250
    Language: English
    Note: Front Cover -- The Determination of Carboxylic Functional Groups -- Copyright Page -- Table of Contents -- Preface -- CHAPTER 1. INTRODUCTION -- CHAPTER 2. THE DETERMINATION OF CARBOXYLIC ACIDS -- 1. GENERAL -- 2. ACID-BASE EQUILIBRIUM IN WATER -- 3 . ACID-BASE EQUILIBRIUM IN NON-AQUEOUS MEDIA -- 4 . TITRIMETRIC DETERMINATION OF ACIDS -- 5. SPECTROPHOTOMETRIC METHODS -- 6. CHROMATOGRAPHIC METHODS -- 7. COUNTERCURRENT SEPARATION OF ORGANIC ACIDS -- 8. ELECTROPHORETIC SEPARATION OF ORGANIC ACIDS -- 9 . POLAROGRAPHY OF ORGANIC ACIDS -- 10. SOME OTHER CHEMICAL METHODS -- REFERENCES -- CHAPTER 3. THE DETERMINATION OF ACID ANHYDRIDES AND ACID CHLORIDES -- A. ACID ANHYDRIDES -- B. ACID CHLORIDES -- REFERENCES -- CHAPTER 4. THE DETERMINATION OF ESTERS -- 1. GENERAL -- 2. SAPONIFICATION METHODS -- 3 . SOME SPECIFIC METHODS -- 4. SPECTROSCOPIC METHODS -- 5. CHROMATOGRAPHY OF ESTERS -- 6 . SOME OTHER PHYSICAL METHODS -- 7. DETERMINATION OF LACTONES -- REFERENCES -- CHAPTER 5. DETERMINATION OF AMIDES -- 1. GENERAL -- 2. GENERAL METHODS -- 3 . USE OF GRIGNARD'S REAGENT -- 4. SPECIFIC METHODS FOR PRIMARY AMIDES -- REFERENCES -- CHAPTER 6. THE ANALYSIS OF BINARY AND TERNARY MIXTURES -- 1. GENERAL -- 2. DIFFERENTIATION OF ACIDS -- 3. MIXTURES OF ACIDS AND ANHYDRIDES -- 4. MIXTURES OF ACIDS AND ACID CHLORIDES -- 5. MIXTURES OF ACIDS AND ESTERS -- 6. MIXTURES OF ACIDS AND AMIDES -- REFERENCES -- INDEX.
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  • 9
    Online Resource
    Online Resource
    Oxford :Oxford University Press, Incorporated,
    Keywords: Population biology-Statistical methods. ; Sampling (Statistics). ; Electronic books.
    Description / Table of Contents: This advanced text focuses on the uses of distance sampling to estimate the density and abundance of biological populations. It addresses new methodologies, new technologies and recent developments in statistical theory and is the follow up companion to Introduction to Distance Sampling (OUP, 2001).
    Type of Medium: Online Resource
    Pages: 1 online resource (435 pages)
    Edition: 1st ed.
    ISBN: 9780191545191
    DDC: 591.7880727
    Language: English
    Note: Intro -- Contents -- 1 Introduction to advanced distance sampling -- 2 General formulation for distance sampling -- 2.1 Introduction -- 2.2 CDS revisited -- 2.2.1 Conventional line transect estimator -- 2.2.2 Conventional point transect estimator -- 2.3 Horvitz-Thompson: a versatile estimator -- 2.3.1 Animals that occur as individuals -- 2.3.2 Animals that occur in clusters -- 2.3.3 CDS estimators -- 2.4 Maximum likelihood estimation -- 2.4.1 'Covered' animals -- 2.4.2 Random detection with known probability -- 2.4.3 CDS likelihoods -- 2.5 Summary so far and preview of advances -- 2.5.1 Summary -- 2.5.2 Preview of advances -- 2.6 Advanced methods for detection function estimation -- 2.6.1 Multiple covariate distance sampling -- 2.6.2 Mark-recapture distance sampling -- 2.6.3 Estimation when & -- #960 -- (y) is unknown -- 2.7 Estimating animal density surfaces -- 2.7.1 The count method -- 2.7.2 The waiting distance method -- 2.7.3 Cluster size surface estimation -- 2.8 Survey design -- 2.8.1 Likelihood-based inference -- 2.8.2 Design-based inference -- 2.8.3 Adaptive distance sampling -- 2.9 Model selection -- 2.10 Summary -- 3 Covariate models for the detection function -- 3.1 Introduction -- 3.2 A conditional likelihood framework for distance sampling -- 3.3 Line transect sampling -- 3.3.1 The conditional likelihood -- 3.3.2 Incorporating covariates into semiparametric models for the detection function -- 3.3.3 Abundance estimation -- 3.4 Point transect sampling -- 3.5 Example -- 3.6 Discussion -- 4 Spatial distance sampling models -- 4.1 Introduction -- 4.2 Spatial line transect models -- 4.2.1 Deriving a likelihood -- 4.2.2 A likelihood based on inter-detection distances -- 4.2.3 Clustered populations -- 4.3 Practical implementations of spatial line transect models -- 4.3.1 A waiting distance model -- 4.3.2 A count model. , 4.4 Spatial distribution of Antarctic minke whales -- 4.5 Spatial point transect models -- 4.5.1 Deriving a likelihood -- 4.5.2 A point transect count model -- 4.6 Discussion -- 5 Temporal inferences from distance sampling surveys -- 5.1 Introduction -- 5.2 Concepts -- 5.2.1 Sampling and population variation -- 5.2.2 Sampling covariance -- 5.2.3 Empirical and process models -- 5.2.4 Trend -- 5.2.5 Abundance as a fixed or random quantity -- 5.3 Trend estimation from global abundance estimates -- 5.3.1 Graphical exploration -- 5.3.2 Linear trend models -- 5.3.3 Smoothing -- 5.3.4 Trend estimation when samples covary -- 5.4 Spatio-temporal analysis -- 5.4.1 Transect-level models of trend -- 5.4.2 Spatio-temporal modelling -- 5.5 Process models -- 5.5.1 State-space models -- 5.5.2 Generalizing state-space models -- 5.6 Other analysis methods -- 5.6.1 Time series methods -- 5.6.2 Quality control methods -- 5.7 Survey design -- 5.7.1 Repeating transects -- 5.7.2 Sample size -- 5.7.3 Planning long-term studies -- 6 Methods for incomplete detection at distance zero -- 6.1 Introduction -- 6.2 Likelihood and Horvitz-Thompson -- 6.2.1 Constant detection probability -- 6.2.2 Detection probability changing with distance -- 6.2.3 Independence issues -- 6.2.4 Multiple covariates -- 6.2.5 Unobserved heterogeneity -- 6.3 State and observation models -- 6.3.1 State models -- 6.3.2 Observation models -- 6.3.3 Observation configurations -- 6.4 Example data -- 6.5 Estimation for independent configuration -- 6.5.1 Distance only -- 6.5.2 Distance and covariates -- 6.6 Estimation for trial configuration -- 6.6.1 Distance and covariates -- 6.6.2 Distance, covariates, and responsive movement -- 6.7 Estimation for removal configuration -- 6.8 Dealing with availability bias -- 6.8.1 Static availability -- 6.8.2 Hazard-rate models for dynamic availability. , 6.8.3 Discrete availability: animal-based -- 6.8.4 Discrete availability: cue-based -- 6.8.5 Intermittent availability -- 6.8.6 Design-based availability estimation -- 6.9 Special topics -- 6.9.1 Uncertain duplicate identification -- 6.9.2 When should double-observer methods be used? -- 6.10 Field methods -- 6.10.1 Marked animals -- 6.10.2 Observation configuration -- 6.10.3 Data collection and recording -- 7 Design of distance sampling surveys and Geographic Information Systems -- 7.1 The potential role of GIS in survey design -- 7.2 Automated survey design -- 7.2.1 Point transect design -- 7.2.2 Line transect design using lines of fixed length -- 7.2.3 Line transect design using lines that span the full width of the survey region -- 7.2.4 Zigzag samplers -- 7.3 Estimation for uneven coverage probability designs -- 7.3.1 Objects that occur singly -- 7.3.2 Objects that occur in clusters -- 7.3.3 Variance estimation -- 7.4 Choosing between survey designs by simulation -- 8 Adaptive distance sampling surveys -- 8.1 Introduction -- 8.2 Design-unbiased adaptive point transect surveys -- 8.2.1 Survey design -- 8.2.2 Estimation -- 8.2.3 Simulated example -- 8.2.4 Discussion -- 8.3 Design-unbiased adaptive line transect surveys -- 8.3.1 Survey design -- 8.3.2 Estimation -- 8.3.3 Discussion -- 8.4 Fixed-effort adaptive line transect surveys -- 8.4.1 Survey design -- 8.4.2 Estimation -- 8.4.3 Simulation -- 8.4.4 Discussion -- 9 Passive approaches to detection in distance sampling -- 9.1 Introduction -- 9.2 Trapping webs -- 9.2.1 Density estimation -- 9.2.2 Including data from recaptures -- 9.2.3 Design of trapping webs -- 9.2.4 An example -- 9.2.5 A critique of the trapping web -- 9.3 Trapping line transects -- 9.3.1 Density estimation -- 9.3.2 Including data from recaptures -- 9.3.3 Design of trapping line transects -- 9.3.4 An example. , 9.3.5 A critique of the trapping line transect -- 9.4 Discussion and summary -- 10 Assessment of distance sampling estimators -- 10.1 Introduction -- 10.1.1 Notation -- 10.2 Estimation framework -- 10.3 Model and design -- 10.3.1 Model-based inference -- 10.3.2 Design-based inference -- 10.3.3 Distance sampling: a composite approach -- 10.4 Simulation framework -- 10.4.1 Testing the design -- 10.4.2 Testing the model -- 10.4.3 Testing the full line transect estimation procedure -- 10.5 Example: testing the design -- 10.5.1 Testing equal coverage designs for var( N) -- 10.5.2 A design without equal coverage probability -- 10.6 Example: non-uniformity within the strip -- 10.6.1 Estimation of N[sub(c)] -- 10.6.2 Asymptotic result when & -- #952 -- is estimated -- 10.7 Example: full estimation procedure -- 10.8 Trial by simulation: a completely model-based approach -- 10.9 Summary -- 11 Further topics in distance sampling -- 11.1 Distance sampling in three dimensions -- 11.1.1 Three-dimensional line transect sampling -- 11.1.2 Three-dimensional point transect sampling -- 11.2 Conventional distance sampling: full likelihood examples -- 11.2.1 Line transects: simple examples -- 11.2.2 Point transects: simple examples -- 11.2.3 Some numerical confidence interval comparisons -- 11.3 Line transect surveys with random line length -- 11.3.1 Introduction -- 11.3.2 Line transect sampling with fixed n and random L, under Poisson object distribution -- 11.3.3 Technical comments -- 11.3.4 Discussion -- 11.4 Models for the search process -- 11.4.1 Continuous hazard-rate models -- 11.4.2 Discrete hazard-rate models -- 11.4.3 Further modelling of the detection process -- 11.5 Combining mark-recapture and distance sampling surveys -- 11.6 Combining removal methods and distance sampling -- 11.6.1 Introduction -- 11.6.2 Combining removal methods with distance sampling. , 11.7 Point transect sampling of cues -- 11.7.1 Introduction -- 11.7.2 Estimation -- 11.8 Migration counts -- 11.8.1 Background -- 11.8.2 Modelling migration rate -- 11.8.3 Modelling detection probabilities -- 11.8.4 An example: gray whales -- 11.9 Estimation with distance measurement errors -- 11.9.1 Conventional distance sampling: g(0) = 1 -- 11.9.2 Independent multiplicative measurement errors -- 11.9.3 Mark-recapture distance sampling: p(0) < -- 1 -- 11.9.4 Maximum likelihood vs pdf correction approach -- 11.10 Relating object abundance to population abundance for indirect sampling -- 11.10.1 Introduction -- 11.10.2 Discrete-time modelling -- 11.10.3 Continuous-time modelling -- 11.10.4 Conclusions -- 11.11 Goodness of fit tests and q-q plots -- 11.11.1 Quantile-quantile plots -- 11.11.2 Kolmogorov-Smirnov test -- 11.11.3 Cramér-von Mises test -- 11.11.4 The Cramér-von Mises family of tests -- 11.12 Pooling robustness -- References -- Index -- A -- B -- C -- D -- E -- F -- G -- H -- I -- K -- L -- M -- N -- P -- Q -- R -- S -- T -- V -- Z.
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  • 10
    Online Resource
    Online Resource
    San Diego :Elsevier Science & Technology,
    Keywords: Cyanogen compounds -- Analysis. ; Electronic books.
    Type of Medium: Online Resource
    Pages: 1 online resource (153 pages)
    Edition: 1st ed.
    ISBN: 9781483278612
    Language: English
    Note: Front Cover -- Analytical Methods for Organic Cyano Groups -- Copyright Page -- Table of Contents -- PREFACE -- CHAPTER 1. INTRODUCTION -- References -- PART A: CHEMICAL METHODS -- GENERAL INTRODUCTION -- CHAPTER 2. REACTIONS OF (ADDITION TO) THE CYANO GROUP -- Introduction -- 1. Reduction: -CN-CH2-NH2 -- 2. Hydrolysis -- 3. Addition of Hydrogen Sulphide -- 4. Addition of Alcohols -- 5. Addition of Ammonia -- 6. Addition of Hydroxylamine -- 7. Addition of Hydrazine -- 8. Addition of Mercaptans -- 9. Addition of Polyphenols -- 10. Addition of Grignard Reagent -- 11. Preparation of N-(2-Chloroalkyl) amides -- 12. Formation of Metal Complexes -- References -- CHAPTER 3. REACTIONS OF GROUPS ACTIVATED BY THE CYANO GROUP -- Introduction -- 1. α,β-Unsaturated Nitriles -- 2. Compounds Containing the - CH2CN or =CHCN Group -- 3. Compounds Containing the - NH - or NH2 Group Attached to -CN -- References -- CHAPTER 4. REACTIONS OF GROUPS SENSIBLY UNAFFECTED BY THE CYANO GROUP -- 1. Higher Aliphatic Nitriles -- 2.β,γ-Unsaturated Nitriles -- 3. Aromatic Groups in Nitriles -- 4. Halogen Atoms in Trichloroacetonitrile -- 5. Azo Group in Azobisisobutyronitrile -- 6. Hydrazo Group in 2,2'-Hydrazobisisobutyronitrile -- 7. Ester Group in Nitriles -- 8. Amino Groups (not Directly Linked to a Cyano Group) -- 9. Amidino or Guanidino Group in Dicyanodiamide -- 10. Cobalt in Vitamin B12 (Cyanocobalamin) -- 11. 5,6-Dimethylbenzimidazole in Vitamin B12 -- References -- CHAPTER 5. DEGRADATION REACTIONS DURING WHICH THE CYANO GROUP REMAINS INTACT -- Introduction -- 1. Pyrolysis without Added Reagent -- 2. Pyrolysis in Presence of Oxidising Agents -- 3. Pyrolysis in Presence of a Base -- 4. Reductive Fission of N-cyano Compounds -- 5. Hydrolytic Fission of Cyanohydrins -- 6. Formation of Bromine Cyanide, BrCN. , 7. Elimination of the Cyano Group in the Analytical Methods for Ethyl Dimethylphosphoramidocyanidate (Tabun) -- 8. Elimination of the Cyano Group as Hydrocyanic Acid in Determination of Vitamin B12 -- 9. Formation of Thiocyanic Acid by Reaction with Sulphur -- References -- CHAPTER 6. DEGRADATION REACTIONS INVOLVING DESTRUCTION OF THE CYANO GROUP -- References -- CHAPTER 7. MISCELLANEOUS CHEMICAL METHODS -- References -- PART B: PHYSICAL METHODS -- GENERAL INTRODUCTION -- CHAPTER 8. SPECTROSCOPIC AND SPECTROPHOTOMETRIC METHODS -- 1. Infrared -- 2. Ultraviolet and Visible -- 3. Mass Spectrometry -- 4. Flame Spectroscopy -- 5. Nuclear Magnetic Resonance -- References -- CHAPTER 9. CHROMATOGRAPHIC METHODS -- 1. Gas Chromatography -- 2. Other Chromatographic Methods, Principally PC and TLC -- References -- CHAPTER 10. ION EXCHANGE -- References -- CHAPTER 11. POLAROGRAPHY -- References -- CHAPTER 12. AZEOTROPIC DISTILLATION -- References -- AUTHOR INDEX -- SUBJECT INDEX.
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