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  • 1
    Electronic Resource
    Electronic Resource
    N-Arylmaleimide derivatives (2000)
    Springer
    Journal of chemical crystallography 30 (2000), S. 563-571 
    Details
    ISSN: 1572-8854
    Keywords: Maleimide ; crystal structure ; photopolymerization ; monomer ; conformation
    Source: Springer Online Journal Archives 1860-2000
    Topics: Geosciences , Physics
    Notes: Abstract Nine phenyl substituted N-phenylmaleimide monomers for photopolymerization studies have been characterized by x-ray crystallography. Structures for N-(2′-t-butylphenyl)maleimide (1), P21/n, a = 10.197(3) Å, b = 11.904(4) Å, c = 10.496(5) Å, β = 100.61(3)° N-(2′-trifluoromethylphenyl)maleimide (2), P21/c, a = 11.763(8) Å, b = 10.699(9) Å, c = 8.284(5) Å, β = 90.02(5)° N-(2′,6′-diisopropylphenyl)maleimide hemibenzene solvate (3), Pc, a = 16.747(6) Å, b = 8.552(3) Å, c = 12.899(4) Å, β = 105.08(3)° N-(2′,6′-diisopropylphenyl) maleimide (unsolvated) (4), C2/c, a = 28.146(10) Å, b = 8.434(4) Å, c = 12.881(4) Å, β = 92.20(4)° N-(2′-bromo-3′,5′-bis(trifluoromethyl)phenyl) maleimide (5), P21/n, a = 8.7115(16) Å, b = 16.125(3) Å, c = 9.6707(19) Å, β = 99.757(15)° N-(2′-phenylphenyl)maleimide (6), P21/n, a = 8.519(4) Å, b = 13.742(5) Å, c = 11.147(4) Å, β = 92.25(3)° N-(4′-methoxyphenyl)maleimide (7), P21/n, a = 9.320(3) Å, b = 6.621(2) Å, c = 16.059(6) Å, β = 99.58(3)° N-(2′-trifluoromethylphenyl)-2-methylmaleimide (8), Fdd2, a = 43.362(12) Å, b = 8.202(2) Å, c = 12.720(4) Å and N-(2′-trifluoromethylphenyl)-2-methanosuccinimide (9), Cc, a = 7.708(2) Å, b = 22.191(9) Å, c = 7.137(2) Å, β = 115.76(2)° are described. Molecules with bulky 2′-substituents show larger rotations between the mean phenyl and maleimide ring planes, and varying degrees of distortion to the imide group.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1023/A:1011345925270
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  • 2
    Electronic Resource
    Electronic Resource
    Discrimination in resolving systems II: Ephedrine-substituted mandelic acids (1995)
    New York, NY [u.a.] : Wiley-Blackwell
    Chirality 7 (1995), S. 652-676 
    Details
    ISSN: 0899-0042
    Keywords: diastereomeric salts ; molecular recognition ; hydrogen bonding ; polymorphism ; thermal analysis ; crystallography ; Chemistry ; Organic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Binary diastereomeric (-) (1R,2S)-ephedrine salts of various mandelic acids obtained from 95% ethanol show considerable differences in solubility. Structures and some properties of the less-soluble (L) and more-soluble (M) solid phases of (-)-ephedrine with unsubstituted mandelic acid, 2-, 3-, and 4-monosubstituted halo (F, Cl, Br) mandelic acids, and 3- and 4-methylmandelic acids have been determined. Salts were found to be binary, without solvent of crystallization, and composed of double-layered arrays of alternating anions and cations linked by H-bonds normal to the layers. H-bonding links charged donors and acceptors usually along a crystallographic 2-fold screw axis. A striking discrimination is evident in that the (2R)-mandelate salts typically display a compact four-atom chain as the H-bonding repeating unit [+N - H…O( - C- - O)…H-N′, C21(4)] while the (2S)-mandelate salts adopt a more dimensionally variable six-atom chain repeating unit [+N - H…O - C- - O…H - N′, C22(6)]. Two distinct packing schemes display the shorter H-bonding chain of the (2R)-mandelates which always occurs with ephedrinium ions in the fully extended conformation. Slightly greater packing efficiency and H-bonding energies of the (2R)-mandelate salts correlates with increased fusion points, lower solubilities (95% ethanol), and higher heats of fusion relative to the phase adopted by their diastereoisomers. In contrast, (2S)-mandelate salts exhibit considerably more structural variability involving all three major ephedrinium conformations, and at least four distinct packing motifs. Mandelates with larger 3′-substituents (Cl, Br, methyl) show similar property discriminations, but these occur with an opposing trend, that is, between phases in which the less-soluble salts contain (2S)-mandelates. Salts with 2-bromomandelate do not show property disparities and their structures are dissimilar to the other phases. © 1995 Wiley-Liss, Inc.
    Additional Material: 11 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/chir.530070816
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  • 3
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    Acoustic intensity fluctuations induced by South China Sea internal tides and solitons (2006)
    IEEE
    Details
    Publication Date: 2022-05-25
    Description: Author Posting. © IEEE, 2004. This article is posted here by permission of IEEE for personal use, not for redistribution. The definitive version was published in IEEE Journal of Oceanic Engineering 29 (2004): 1249-1263, doi:10.1109/JOE.2004.834173.
    Description: Between late April and May 23, 2001, a suite of acoustic and oceanographic sensors was deployed by a team of U.S., Taiwan, and Singapore scientists in the northeastern South China Sea to study the effects of ocean variability on low-frequency sound propagation in a shelfbreak environment. The primary acoustic receiver was an L-shaped hydrophone array moored on the continental shelf that monitored a variety of signals transmitted along and across the shelfbreak by moored sources. This paper discusses and contrasts the fluctuations in the 400-Hz signals transmitted across the shelfbreak and measured by the vertical segment of the listening array on two different days, one with the passage of several huge solitons that depressed the shallow isotherms to near the sea bottom and one with a much less energetic internal wavefield. In addition to exhibiting large and rapid temporal changes, the acoustic data show a much more vertically diffused sound intensity field as the huge solitons occupied and passed through the transmission path. Using a space-time continuous empirical sound-speed model based on the moored temperature records, the observed acoustic intensity fluctuations are explained using coupled-mode physics.
    Description: This work was supported by the U.S. Office of Naval Research.
    Keywords: Intensity fluctuations ; Nonlinear internal waves ; Shallow water acoustics ; South China Sea (SCS)
    Repository Name: Woods Hole Open Access Server
    Type: Article
    Format: 1369570 bytes
    Format: application/pdf
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    PAPER (OA)
  • 4
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    Platform to Enable Combined Measurement of Dopamine and Neural Activity (2017)
    American Chemical Society (ACS)
    Details
    Publication Date: 2017-02-18
    Description: Analytical Chemistry DOI: 10.1021/acs.analchem.6b03642
    Print ISSN: 0003-2700
    Electronic ISSN: 1520-6882
    Topics: Chemistry and Pharmacology
    Published by American Chemical Society (ACS)
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