Description: A high-resolution multiproxy geochemical approach was applied to the sediments of Laguna Potrok Aike in an attempt to reconstruct moist and dry periods during the past 16 000 years in southeastern Patagonia. The age–depth model is inferred from AMS 14C dates and tephrochronology, and suggests moist conditions during the Lateglacial and early Holocene (16 000–8700 cal. BP) interrupted by drier conditions before the beginning of the Holocene (13 200–11 400 cal. BP). Data also imply that this period was a major warm phase in southeastern Patagonia and was approximately contemporaneous with the Younger Dryas chronozone in the Northern Hemisphere (12 700–11 500 cal. BP). After 8650 cal. BP a major drought may have caused the lowest lake level of the record. Since 7300 cal. BP, the lake level rose and was variable until the 'Little Ice Age', which was the dominant humid period after 8650 cal. BP.

Description: Seismic reflection studies in the maar lake Laguna Potrok Aike (51°58? S, 70°23? W) revealed an erosional unconformity associated with a sub-aquatic lake-level terrace at a water depth of 30m. Radiocarbon-dated, multi-proxy sediment studies of a piston core from this location indicate that the sediment below this discontinuity has an age of 45kyr BP (Oxygen Isotope Stage 3), and was deposited during an interval of high lake level. In comparison to the Holocene section, geochemical indicators of this older part of the record either point towards a different sediment source or to a different transport mechanism for Oxygen Isotope Stage 3 sediments. Holocene sedimentation started again before 6790cal. yr BP, providing a sediment record of hydrological variability until the present. Geochemical and isotopic data indicate a fluctuating lake level until 5310cal. yr BP. During the late Holocene the lake level shows a receding tendency. Nevertheless, the lake level did not drop below the 30m terrace to create another unconformity. The geochemical characterization of volcanic ashes reveals evidence for previously unknown explosive activity of the Reclús and Mt. Burney volcanoes during Oxygen Isotope Stage 3.

Description: The 106 m long composite profile from site 2 of ICDP expedition 5022 (PASADO) at Laguna Potrok Aike documents a distinct change in sedimentation patterns from pelagic sediments at the top to dominating mass movement deposits at its base. The main lithological units correspond to the Holocene, to the Lateglacial and to the last glacial period and can be interpreted as the result of distinct environmental variations. Overflow conditions might have been achieved during the last glacial period, while signs of desiccation are absent in the studied sediment record. Altogether, 58 radiocarbon dates were used to establish a consistent age-depth model by applying the mixed-effect regression procedure which results in a basal age of 51.2 cal. ka BP. Radiocarbon dates show a considerable increase in scatter with depth which is related to the high amount of reworking. Validation of the obtained chronology was achieved with geomagnetic relative paleointensity data and tephra correlation.

Description: The sediment record from Rodderberg potentially provides a climate and environmental record spanning at least the last ca 130 ka. Results from a low resolution pilot study reveal characteristic fluctuations that can be related to global climate variability as reflected in marine isotope stages and document the potential of this site for continuous and high-resolution investigations of the Middle to Late Pleistocene. Here we document the tentative lithology drilled, and show how the elemental composition can be interpreted with regard to lake level fluctuations, related redox conditions, but also to grain-size distribution and changes in lacustrine productivity. Finally, based on major lithological changes, a preliminary depth/age model is suggested that allows reassessing published luminescence ages from the same site.

Description: The sedimentary archive from Laguna Potrok Aike is the only continuous record reaching back to the last Glacial period in continental southeastern Patagonia. Located in the path of the Southern Hemisphere westerly winds and in the source region of dust deposited in Antarctica during Glacial periods, southern Patagonia is a vantage point to reconstruct past changes in aeolian activity. Here we use high-resolution rock-magnetic and physical grain size data from site 2 of the International Continental scientific Drilling Program (ICDP) Potrok Aike maar lake Sediment Archive Drilling prOject (PASADO) in order to develop magnetic proxies of dust and wind intensity at 52°S since 51,200 cal BP. Rock-magnetic analysis indicate the magnetic mineral assemblage is dominated by detrital magnetite. Based on the estimated flux of magnetite to the lake and comparison with distal dust records from the Southern Ocean and Antarctica, kLF is interpreted as a dust indicator in the dust source of southern Patagonia at the millennial time scale, when ferrimagnetic grain size and coercivity influence is minimal. Comparison to physical grain-size data indicates that the median destructive field of isothermal remanent magnetisation (MDFIRM) mostly reflects medium to coarse magnetite bearing silts typically transported by winds for short-term suspension. Comparison with wind-intensity proxies from the Southern Hemisphere during the last Glacial period and with regional records from Patagonia since the last deglaciation including marine, lacustrine and peat bog sediments as well as speleothems reveals similar variability with MDFIRM up to the centennial time scale. MDFIRM is interpreted as a wind-intensity proxy independent of moisture changes for southeastern Patagonia, with stronger winds capable of transporting coarser magnetite bearing silts to the lake.

Description: The Schwalbenberg II loess-paleosol sequence (LPS) denotes a key site for Marine Isotope Stage (MIS 3) in Western Europe owing to eight succeeding cambisols, which primarily constitute the Ahrgau Subformation. Therefore, this LPS qualifies as a test candidate for the potential of temporal high-resolution geochemical data obtained X-ray fluorescence (XRF) scanning of discrete samplesproviding a fast and non-destructive tool for determining the element composition. The geochemical data is first contextualized to existing proxy data such as magnetic susceptibility (MS) and organic carbon (Corg) and then aggregated to element log ratios characteristic for weathering intensity [LOG (Ca/Sr), LOG (Rb/Sr), LOG (Ba/Sr), LOG (Rb/K)] and dust provenance [LOG (Ti/Zr), LOG (Ti/Al), LOG (Si/Al)]. Generally, an interpretation of rock magnetic particles is challenged in western Europe, where not only magnetic enhancement but also depletion plays a role. Our data indicates leaching and top-soil erosion induced MS depletion at the Schwalbenberg II LPS. Besides weathering, LOG (Ca/Sr) is susceptible for secondary calcification. Thus, also LOG (Rb/Sr) and LOG (Ba/Sr) are shown to be influenced by calcification dynamics. Consequently, LOG (Rb/K) seems to be the most suitable weathering index identifying the Sinzig Soils S1 and S2 as the most pronounced paleosols for this site. Sinzig Soil S3 is enclosed by gelic gleysols and in contrast to S1 and S2 only initially weathered pointing to colder climate conditions. Also the Remagen Soils are characterized by subtle to moderate positive excursions in the weathering indices. Comparing the Schwalbenberg II LPS with the nearby Eifel Lake Sediment Archive (ELSA) and other more distant German, Austrian and Czech LPS while discussing time and climate as limiting factors for pedogenesis, we suggest that the lithologically determined paleosols are in-situ soil formations. The provenance indices document a Zr-enrichment at the transition from the Ahrgau to the Hesbaye Subformation. This is explained by a conceptual model incorporating multiple sediment recycling and sorting effects in eolian and fluvial domains.

Description: A 3 m-long continuous sediment record recovered from Laguna Meseta (LME), one of the lakes located on Meseta Chile Chico, Central Patagonia, Chile. Its radiocarbon chronology documents sediments of the last ~10,000 years indicating a minimum age for postglacial ice-free lacustrine conditions due to a westward retreat of the Large Patagonian Ice sheet. At this time, lacustrine productivity reached its maximum and decreased afterwards. Between 5,500 and 4,600 cal yr BP, a major shift towards allochthonous sediment accumulation occurred, caused by an abrupt increase in clastic deposition from basaltic lithologies of the Meseta Chile Chico. This episode correlates with the precipitation-driven Mid-Holocene glacier advance of Patagonian glaciers, suggesting a persisting glacial influence on the Meseta Chile Chico. After 4,600 cal yr BP wetter climate conditions returned to feed LME with fluvial sediments until a stepped decrease around 1,000 cal yr BP. Thereupon, lacustrine productivity distinctly increased and stabilized around 300 cal yr BP. Our reconstructions and comparisons with other regional paleoenvironmental studies indicate that environmental conditions of LME were mainly controlled by humidity changes on the Meseta Chile Chico and reflect Holocene climate variability.

Description: This study provides a detailed geochemical record of one of the most detailed loess-paleosol sequence (LPS) in Hungary covering Marine Isotope Stage (MIS) 6 to MIS 2. Süttő is situated in the northwestern Carpathian Basin at the transition between oceanic and continental climate. We investigated weathering intensity, dust provenance and sedimentation dynamics by high-resolution X-ray fluorescence (XRF) scanning of discrete samples in comparison with quantitative XRF and other published proxy data such as grain-size, magnetic susceptibility and micromorphology. Multivariate statistics unravel pedogenesis in terms of decalcification and grain-size dynamics as processes controlling the elemental composition. Furthermore, high-resolution chemostratigraphy indicates geochemical homogeneity for mature MIS 5 paleosols and the modern soil. Together with the A-CN-K plot providing no hint for K-feldspar weathering, semi-arid continental paleoenvironmental conditions are considered as prevailing. Dust provenance is studied by geochemical reference literature data from potential ultimate dust source areas, Th/metal ratios and comparison with the composition of the upper continental crust (UCC). Results indicate a felsic rock composition and a stable dust source, albeit immediate (adjacent Danube floodplains) and ultimate dust sources (surrounding mountain belts) need to be distinguished. According to the Sr-K-Rb plot, the Austroalpine cover nappes area northwest of Süttő might be the dominant ultimate dust source. The weathering-resistant elements Al, Ti and Zr as well as Zr/metal ratios indicate Zr addition and thus strongest sediment sorting and/ or recycling during MIS 6. Since Al, Ti and Zr show minimal correlations with grain-size, we suggest a cascade-alike transport pathway from ultimate source to sink involving multiple sediment recycling and sorting cycles in both fluvial and eolian domains. Therefore, this study highlights how high-resolution qualitative geochemical data contributes to a better understanding of paleoenvironmental and sedimentation dynamics at LPS. Application of such a versatile geochemical screening tool is of broad interest to the scientific community working on (terrestrial) paleoenvironmental archives that are commonly discretely sampled.

Description: This dataset contains a revised age model for 106 m long composite core 2CP of ICDP project 5022 (PASADO), Laguna Potrok Aike, Patagonia, Argentina. This age model is based on radiocarbon and OSL dates along with paleomagnetic information.