In:
Angewandte Chemie International Edition, Wiley, Vol. 58, No. 23 ( 2019-06-03), p. 7692-7696
Abstract:
Efficient adsorptive separation of propylene/propane (C 3 H 6 /C 3 H 8 ) is highly desired and challenging. Known strategies focus on either the thermodynamic or the kinetic mechanism. Here, we report an interesting reactivity of a metal–organic framework that improves thermodynamic and kinetic adsorption selectivity simultaneously. When the metal–organic framework is heated under oxygen flow, half of the soft methylene bridges of the organic ligands are selectively oxidized to form the more polar and rigid carbonyl bridges. Mixture breakthrough experiments showed drastic increase of C 3 H 6 /C 3 H 8 selectivity from 1.5 to 15. For comparison, the C 3 H 6 /C 3 H 8 selectivities of the best‐performing metal–organic frameworks Co‐MOF‐74 and KAUST‐7 were experimentally determined to be 6.5 and 12, respectively. Gas adsorption isotherms/kinetics, single‐crystal X‐ray diffraction, and computational simulations revealed that the oxidation gives additional guest recognition sites, which improve thermodynamic selectivity, and reduces the framework flexibility, which generate kinetic selectivity.
Type of Medium:
Online Resource
ISSN:
1433-7851
,
1521-3773
DOI:
10.1002/anie.201902209
Language:
English
Publisher:
Wiley
Publication Date:
2019
detail.hit.zdb_id:
2011836-3
detail.hit.zdb_id:
123227-7
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