In:
Chemische Berichte, Wiley, Vol. 130, No. 10 ( 1997-10), p. 1539-1546
Abstract:
The synthesis of the chiral tin bromides 1 ‐ 4 and hydrides 5 ‐ 8 , containing the potentially bidentate, optically active 2‐[ (1 S/R)‐ 1 ‐dimethylaminoethyl]phenyl and 2 ‐[( 1 S ) ‐ 1 ‐dimethylamino‐2,2‐dimethylpropyl]phenyl ligands, is reported. The tin hydrides 5‐ 8 , with the tin atom as the stereogenic centre, were isolated as diastereomeric mixtures with diastereomeric ratios of dr = 50:50 up to dr = 80:20. The absolute configuration of (—) ‐ (1 S )‐ 1 ‐ (2‐bromophenyl) ‐2,2‐dimethylpropylamine [( S )‐ 10 ] was determined by single‐crystal X‐ray structure analysis.
Type of Medium:
Online Resource
ISSN:
0009-2940
DOI:
10.1002/cber.v130:10
DOI:
10.1002/cber.19971301030
Language:
English
Publisher:
Wiley
Publication Date:
1997
detail.hit.zdb_id:
1475009-0
Permalink