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  • 1
    In: Atmospheric Chemistry and Physics, Copernicus GmbH, Vol. 18, No. 16 ( 2018-08-17), p. 11753-11777
    Abstract: Abstract. We describe the motivation, design, and execution of the Greenhouse gAs Uk and Global Emissions (GAUGE) project. The overarching scientific objective of GAUGE was to use atmospheric data to estimate the magnitude, distribution, and uncertainty of the UK greenhouse gas (GHG, defined here as CO2, CH4, and N2O) budget, 2013–2015. To address this objective, we established a multi-year and interlinked measurement and data analysis programme, building on an established tall-tower GHG measurement network. The calibrated measurement network comprises ground-based, airborne, ship-borne, balloon-borne, and space-borne GHG sensors. Our choice of measurement technologies and measurement locations reflects the heterogeneity of UK GHG sources, which range from small point sources such as landfills to large, diffuse sources such as agriculture. Atmospheric mole fraction data collected at the tall towers and on the ships provide information on sub-continental fluxes, representing the backbone to the GAUGE network. Additional spatial and temporal details of GHG fluxes over East Anglia were inferred from data collected by a regional network. Data collected during aircraft flights were used to study the transport of GHGs on local and regional scales. We purposely integrated new sensor and platform technologies into the GAUGE network, allowing us to lay the foundations of a strengthened UK capability to verify national GHG emissions beyond the project lifetime. For example, current satellites provide sparse and seasonally uneven sampling over the UK mainly because of its geographical size and cloud cover. This situation will improve with new and future satellite instruments, e.g. measurements of CH4 from the TROPOspheric Monitoring Instrument (TROPOMI) aboard Sentinel-5P. We use global, nested, and regional atmospheric transport models and inverse methods to infer geographically resolved CO2 and CH4 fluxes. This multi-model approach allows us to study model spread in a posteriori flux estimates. These models are used to determine the relative importance of different measurements to infer the UK GHG budget. Attributing observed GHG variations to specific sources is a major challenge. Within a UK-wide spatial context we used two approaches: (1) Δ14CO2 and other relevant isotopologues (e.g. δ13CCH4) from collected air samples to quantify the contribution from fossil fuel combustion and other sources, and (2) geographical separation of individual sources, e.g. agriculture, using a high-density measurement network. Neither of these represents a definitive approach, but they will provide invaluable information about GHG source attribution when they are adopted as part of a more comprehensive, long-term national GHG measurement programme. We also conducted a number of case studies, including an instrumented landfill experiment that provided a test bed for new technologies and flux estimation methods. We anticipate that results from the GAUGE project will help inform other countries on how to use atmospheric data to quantify their nationally determined contributions to the Paris Agreement.
    Type of Medium: Online Resource
    ISSN: 1680-7324
    Language: English
    Publisher: Copernicus GmbH
    Publication Date: 2018
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  • 2
    Online Resource
    Online Resource
    Springer Science and Business Media LLC ; 2017
    In:  Nature Vol. 549, No. 7671 ( 2017-09-14), p. 211-218
    In: Nature, Springer Science and Business Media LLC, Vol. 549, No. 7671 ( 2017-09-14), p. 211-218
    Type of Medium: Online Resource
    ISSN: 0028-0836 , 1476-4687
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    Language: English
    Publisher: Springer Science and Business Media LLC
    Publication Date: 2017
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  • 3
    In: Nature, Springer Science and Business Media LLC, Vol. 389, No. 6653 ( 1997-10), p. 835-838
    Type of Medium: Online Resource
    ISSN: 0028-0836 , 1476-4687
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    Language: English
    Publisher: Springer Science and Business Media LLC
    Publication Date: 1997
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  • 4
    Online Resource
    Online Resource
    Springer Science and Business Media LLC ; 1990
    In:  Nature Vol. 347, No. 6292 ( 1990-10), p. 432-433
    In: Nature, Springer Science and Business Media LLC, Vol. 347, No. 6292 ( 1990-10), p. 432-433
    Type of Medium: Online Resource
    ISSN: 0028-0836 , 1476-4687
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    Language: English
    Publisher: Springer Science and Business Media LLC
    Publication Date: 1990
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  • 5
    Online Resource
    Online Resource
    American Geophysical Union (AGU) ; 1998
    In:  Journal of Geophysical Research: Atmospheres Vol. 103, No. D7 ( 1998-04-20), p. 8389-8399
    In: Journal of Geophysical Research: Atmospheres, American Geophysical Union (AGU), Vol. 103, No. D7 ( 1998-04-20), p. 8389-8399
    Abstract: Total ozone measurements have been made at Arosa, Switzerland (47°N), from 1926 through the present day, forming the longest total ozone series in the world. The record has been recently homogenized. Ozone trends are calculated to be −(2.3±0.6)% per decade for annual means (larger losses are found in winter and spring, approximately −4% per decade for trends in January, February, and March) when a simple linear change from 1970 to 1996 is assumed. In addition, total ozone trends are calculated using multiple regression models involving combinations of explanatory variables for the 11‐year solar cycle, local meteorological conditions (the Mount Säntis high‐altitude temperature record), stratospheric aerosol loading from volcanoes, and stratospheric chlorine loading. When the terms for the solar cycle, the stratospheric aerosol loading and the high mountain temperature record were included, the annually averaged ozone trends were found to be −(1.9±0.6)% per decade. While a statistically significant relation is found between total ozone and indices of aerosol loadings of the stratosphere, the recent decrease in total ozone cannot be accounted for by the higher average aerosol content in the second half of the century. Finally, the decrease in ozone in the stratosphere is estimated to be approximately 30% larger than that found for total ozone, when a crude estimate of the increase in tropospheric ozone is included. The acceleration observed in total ozone trends between the 1970s and the 1980s over northern midlatitudes [e.g., Harris et al. , 1997] might be partially attributed to the larger increase in tropospheric ozone in the 1970s.
    Type of Medium: Online Resource
    ISSN: 0148-0227
    Language: English
    Publisher: American Geophysical Union (AGU)
    Publication Date: 1998
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  • 6
    Online Resource
    Online Resource
    American Geophysical Union (AGU) ; 2001
    In:  Journal of Geophysical Research: Atmospheres Vol. 106, No. D19 ( 2001-10-16), p. 22685-22694
    In: Journal of Geophysical Research: Atmospheres, American Geophysical Union (AGU), Vol. 106, No. D19 ( 2001-10-16), p. 22685-22694
    Abstract: Long‐term changes in the vertical ozone distribution over Switzerland are examined for the period 1967–2000. A statistical trend analysis is performed accounting for chemical and dynamical variability. The tropopause pressure, the North Atlantic oscillation (NAO), the Arctic oscillation (AO), and the quasi‐biennial oscillation (QBO) are used as dynamical quantities. In addition, the solar effect and an ozone depletion factor (ODF), which describes the joint effect of stratospheric chlorine and aerosol loading, are included. A term is allowed for an unexplained linear trend. The various influences on ozone are estimated employing stepwise regression. Tropopause pressure and lower stratospheric ozone (10–19 km) variability are found to be strongly linked throughout the year. The NAO‐AO indices show a negative correlation with lower stratospheric ozone in winter‐spring. A positive correlation of NAO‐AO and ozone is found in the middle stratosphere (23–30 km) during late summer to early winter. There is a solar signal in the middle stratosphere which becomes strongly significant in summer. The QBO signal is prominent at the height of the ozone maximum in winter‐spring. The unexplained trends are much larger than the contributions of the ODF, suggesting that mechanisms other than midlatitude in situ chemistry are mostly responsible for the observed ozone loss. In the lowermost stratosphere (10–15 km), the observed ozone trends are found to be caused by dynamics. Above, the residual ozone trend (in percent) is independent of height and in the range of −2% to −5% per decade up to 30 km.
    Type of Medium: Online Resource
    ISSN: 0148-0227
    Language: English
    Publisher: American Geophysical Union (AGU)
    Publication Date: 2001
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    detail.hit.zdb_id: 3094268-8
    detail.hit.zdb_id: 710256-2
    detail.hit.zdb_id: 2016804-4
    detail.hit.zdb_id: 3094181-7
    detail.hit.zdb_id: 3094219-6
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  • 7
    Online Resource
    Online Resource
    AIP Publishing ; 2000
    In:  Review of Scientific Instruments Vol. 71, No. 1 ( 2000-01-01), p. 271-280
    In: Review of Scientific Instruments, AIP Publishing, Vol. 71, No. 1 ( 2000-01-01), p. 271-280
    Abstract: A new, lightweight balloon-borne instrument (DESCARTES) has been developed to make measurements of long-lived trace gases in the stratosphere. DESCARTES is designed to be simple to operate and to fly on small balloons or to “piggyback” on larger payloads. To collect samples, a measured volume of air is passed through a sample tube containing a Carboxen adsorbent. Atmospheric halocarbons are adsorbed and the sample tube is then isolated under an inert nitrogen atmosphere. A number of sample tubes are filled at different altitudes during the flight. After recovery of the instrument the halocarbons are thermally desorbed and quantified using a gas chromatograph with an electron capture detector. In this article we present the design, test, and operation of the instrument with particular emphasis on CFC-11 (CFCl3), the gas for which operation has been optimized.
    Type of Medium: Online Resource
    ISSN: 0034-6748 , 1089-7623
    Language: English
    Publisher: AIP Publishing
    Publication Date: 2000
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  • 8
    In: Journal of Applied Phycology, Springer Science and Business Media LLC, Vol. 25, No. 5 ( 2013-10), p. 1377-1386
    Type of Medium: Online Resource
    ISSN: 0921-8971 , 1573-5176
    Language: English
    Publisher: Springer Science and Business Media LLC
    Publication Date: 2013
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    detail.hit.zdb_id: 1477703-4
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  • 9
    In: Nature, Springer Science and Business Media LLC, Vol. 375, No. 6527 ( 1995-5), p. 131-134
    Type of Medium: Online Resource
    ISSN: 0028-0836 , 1476-4687
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    Language: English
    Publisher: Springer Science and Business Media LLC
    Publication Date: 1995
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  • 10
    In: Global Change Biology, Wiley, Vol. 26, No. 4 ( 2020-04), p. 2320-2335
    Abstract: Projected future climatic extremes such as heatwaves and droughts are expected to have major impacts on emissions and concentrations of biogenic volatile organic compounds (bVOCs) with potential implications for air quality, climate and human health. While the effects of changing temperature and photosynthetically active radiation (PAR) on the synthesis and emission of isoprene, the most abundant of these bVOCs, are well known, the role of other environmental factors such as soil moisture stress are not fully understood and are therefore poorly represented in land surface models. As part of the Wytham Isoprene iDirac Oak Tree Measurements campaign, continuous measurements of isoprene mixing ratio were made throughout the summer of 2018 in Wytham Woods, a mixed deciduous woodland in southern England. During this time, the United Kingdom experienced a prolonged heatwave and drought, and isoprene mixing ratios were observed to increase by more than 400% at Wytham Woods under these conditions. We applied the state‐of‐the‐art FORest Canopy‐Atmosphere Transfer canopy exchange model to investigate the processes leading to these elevated concentrations. We found that although current isoprene emissions algorithms reproduced observed mixing ratios in the canopy before and after the heatwave, the model underestimated observations by ~40% during the heatwave–drought period implying that models may substantially underestimate the release of isoprene to the atmosphere in future cases of mild or moderate drought. Stress‐induced emissions of isoprene based on leaf temperature and soil water content (SWC) were incorporated into current emissions algorithms leading to significant improvements in model output. A combination of SWC, leaf temperature and rewetting emission bursts provided the best model‐measurement fit with a 50% improvement compared to the baseline model. Our results highlight the need for more long‐term ecosystem‐scale observations to enable improved model representation of atmosphere–biosphere interactions in a changing global climate.
    Type of Medium: Online Resource
    ISSN: 1354-1013 , 1365-2486
    URL: Issue
    Language: English
    Publisher: Wiley
    Publication Date: 2020
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