In:
International Journal of Modern Physics B, World Scientific Pub Co Pte Ltd, Vol. 17, No. 28 ( 2003-11-10), p. 5367-5377
Abstract:
We present here a succinct account of the finite-temperature generalisation of the coupled cluster (CC) method. It requires the concept of thermal normal ordered products whose Boltzmann trace is zero. The basic idea is to express the Boltzmann operator as a normal ordered exponential containing cluster operators and a number, and express the free energy as a logarithm of a suitable Boltzmann trace, where only the number part in the ordered exponential survives. The free energy is manifestly extensive. Free energies of Lipkin model and anharmonic oscillators obtained from the grand partition function are discussed as example applications.
Type of Medium:
Online Resource
ISSN:
0217-9792
,
1793-6578
DOI:
10.1142/S021797920302048X
Language:
English
Publisher:
World Scientific Pub Co Pte Ltd
Publication Date:
2003
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