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  • 1
    In: Advanced Materials, Wiley, Vol. 35, No. 1 ( 2023-01)
    Abstract: Growth of dendrites, the low plating/stripping efficiency of Zn anodes, and the high freezing point of aqueous electrolytes hinder the practical application of aqueous Zn‐ion batteries. Here, a zwitterionic osmolyte‐based molecular crowding electrolyte is presented, by adding betaine (Bet, a by‐product from beet plant) to the aqueous electrolyte, to solve the abovementioned problems. Substantive verification tests, density functional theory calculations, and ab initio molecular dynamics simulations consistently reveal that side reactions and growth of Zn dendrites are restrained because Bet can break Zn 2+ solvation and regulate oriented 2D Zn 2+ deposition. The Bet/ZnSO 4 electrolyte enables superior reversibility in a Zn–Cu half‐cell to achieve a high Coulombic efficiency 〉 99.9% for 900 cycles (≈1800 h), and dendrite‐free Zn plating/stripping in Zn–Zn cells for 4235 h at 0.5 mA cm −2 and 0.5 mAh cm −2 . Furthermore, a high concentration of Bet lowers the freezing point of the electrolyte to −92 °C via the molecular‐crowding effect, which ensures the stable operation of the aqueous batteries at −30 °C. This innovative concept of such a molecular crowding electrolyte will inject new vitality into the development of multifunctional aqueous electrolytes.
    Type of Medium: Online Resource
    ISSN: 0935-9648 , 1521-4095
    URL: Issue
    RVK:
    Language: English
    Publisher: Wiley
    Publication Date: 2023
    detail.hit.zdb_id: 1474949-X
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  • 2
    In: Advanced Materials, Wiley, Vol. 35, No. 19 ( 2023-05)
    Abstract: Superconducting quantum interferometer device (SQUID) plays a key role in understanding electromagnetic properties and emergent phenomena in quantum materials. The technological appeal of SQUID is that its detection accuracy for the electromagnetic signal can precisely reach the quantum level of a single magnetic flux. However, conventional SQUID techniques normally can only be applied to a bulky sample and do not have the capability to probe the magnetic properties of micro‐scale samples with small magnetic signals. Herein, it is demonstrated that, based on a specially designed superconducting nano‐hole array, the contactless detection of magnetic properties and quantized vortices in micro‐sized superconducting nanoflakes is realized. An anomalous hysteresis loop and a suppression of Little–Parks oscillation are observed in the detected magnetoresistance signal, which originates from the disordered distribution of the pinned vortices in Bi 2 Sr 2 CaCu 2 O 8+δ . Therefore, the density of pinning centers of the quantized vortices on such micro‐sized superconducting samples can be quantitatively evaluated, which is technically inaccessible for conventional SQUID detection. The superconducting micro‐magnetometer provides a new approach to exploring mesoscopic electromagnetic phenomena of quantum materials.
    Type of Medium: Online Resource
    ISSN: 0935-9648 , 1521-4095
    URL: Issue
    RVK:
    Language: English
    Publisher: Wiley
    Publication Date: 2023
    detail.hit.zdb_id: 1474949-X
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  • 3
    In: Advanced Materials, Wiley
    Abstract: A rational molecular design strategy facilitates the development of a purely organic room‐temperature phosphorescence (RTP) material system with precisely regulated luminescence properties, which surely promotes its functional integration and intelligent application. Here, we propose a functional unit combination strategy to design novel RTP molecules combining a folding unit with diverse luminescent cores. The different luminescent cores are mainly responsible for tunable RTP properties, while the folding unit contributes to the spin–orbit coupling (SOC) enhancement, which makes the RTP material design as workable as the building block principle. By this strategy, a series of color/lifetime‐tunable RTP materials were achieved with unique photo‐responsive RTP enhancement when subjected to UV irradiation, which expands their application scenarios in reusable privacy tags, advanced “4D” encryption, and phase separation analysis of blended polymers. This work suggests a simple and effective strategy to design purely organic RTP materials with tunable color and lifetime, and also provides new application options for photo‐responsive dynamic RTP materials. This article is protected by copyright. All rights reserved
    Type of Medium: Online Resource
    ISSN: 0935-9648 , 1521-4095
    RVK:
    Language: English
    Publisher: Wiley
    Publication Date: 2023
    detail.hit.zdb_id: 1474949-X
    Location Call Number Limitation Availability
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  • 4
    In: Advanced Materials, Wiley, Vol. 34, No. 30 ( 2022-07)
    Abstract: Flexible electrodes that are multilayer, multimaterial, and conformal are pivotal for multifunctional wearable electronics. Traditional electronic circuits manufacturing requires substrate‐supported transfer printing, which limits their multilayer integrity and device conformability on arbitrary surfaces. Herein, a “shrinkage‐assisted patterning by evaporation” (SHAPE) method is reported, by employing evaporation‐induced interfacial strain mismatch, to fabricate auto‐detachable, freestanding, and patternable electrodes. The SHAPE method utilizes vacuum‐filtration of polyaniline/bacterial cellulose (PANI/BC) ink through a masked filtration membrane to print high‐resolution, patterned, and multilayer electrodes. The strong interlayer hydrogen bonding ensures robust multilayer integrity, while the controllable evaporative shrinking property of PANI/BC induces mismatch between the strains of the electrode and filtration membrane at the interface and thus autodetachment of electrodes. Notably, a 500‐layer substrateless micro‐supercapacitor fabricated using the SHAPE method exhibits an energy density of 350 mWh cm −2 at a power density of 40 mW cm −2 , 100 times higher than reported substrate‐confined counterparts. Moreover, a digital circuit fabricated using the SHAPE method functions stably on a deformed glove, highlighting the broad wearable applications of the SHAPE method.
    Type of Medium: Online Resource
    ISSN: 0935-9648 , 1521-4095
    URL: Issue
    RVK:
    Language: English
    Publisher: Wiley
    Publication Date: 2022
    detail.hit.zdb_id: 1474949-X
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  • 5
    Online Resource
    Online Resource
    Society of Exploration Geophysicists ; 2022
    In:  GEOPHYSICS Vol. 87, No. 2 ( 2022-03-01), p. T123-T133
    In: GEOPHYSICS, Society of Exploration Geophysicists, Vol. 87, No. 2 ( 2022-03-01), p. T123-T133
    Abstract: The sea-surface interface between ocean and air is time varying and can be spatially rough as a result of wind, tides, and currents; the shape of this interface changes over time under the influence of wind, tides, etc. As a result, waves impinging on the sea surface are continuously scattered. In the case of marine seismic, the multiple-scattered waves propagate downward into the underwater formation and result in complex seismic responses. To understand the structure of the responses, we have adopted a multistage algorithm for computing the scattered waves at the sea surface. Specifically, we first extrapolate the upgoing incident waves stepwise using thin-slab approximation from the scattering theory based on the De Wolf approximation of the Lippmann-Schwinger equation. Then, we implement the air-water boundary condition at the sea surface. Finally, we use the irregular boundary processing technique to compute the time-varying undulating sea-surface scattered waves from different scattering stages. To overcome the angular limitation of the original parabolic approximation, we introduce a multidirectional parabolic approximation based on computational electromagnetics. Numerical tests indicate that the multistage algorithm presented here can accurately calculate sea-surface scattered waves and should be useful in investigating the structure of marine seismic responses.
    Type of Medium: Online Resource
    ISSN: 0016-8033 , 1942-2156
    RVK:
    Language: English
    Publisher: Society of Exploration Geophysicists
    Publication Date: 2022
    detail.hit.zdb_id: 2033021-2
    detail.hit.zdb_id: 2184-2
    SSG: 16,13
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