In:
Angewandte Chemie, Wiley, Vol. 133, No. 2 ( 2021-01-11), p. 869-877
Abstract:
Currently, most two‐dimensional (2D) metal halide perovskites are of the Ruddlesden–Popper type and contain the thermally unstable methylammonium (MA) molecules, which leads to inferior photovoltaic performance and mild stability. Here we report a new type of MA‐free formamidinium (FA) based low‐dimensional perovskites, featuring a general formula of (PDA)(FA) n −1 Pb n I 3 n +1 with propane‐1,3‐diammonium (PDA) as the organic spacer cation. The perovskite films with well‐oriented crystal grains are attained under the assistance of the FACl additive, where the role of Cl is investigated through the grazing‐incidence X‐ray diffraction technique. The photovoltaic device based on the optimized (PDA)(FA) 3 Pb 4 I 13 film demonstrates a remarkable power conversion efficiency of 13.8 %, the highest record for the FA‐based 2D perovskite solar cells. In addition, compared to (PDA)(MA) 3 Pb 4 I 13 , the MA‐containing analogue and a renowned stable 2D perovskite, both the (PDA)(FA) 3 Pb 4 I 13 films and their derived devices exhibit exceedingly higher thermal stability.
Type of Medium:
Online Resource
ISSN:
0044-8249
,
1521-3757
DOI:
10.1002/ange.202006970
Language:
English
Publisher:
Wiley
Publication Date:
2021
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