In:
Zeitschrift für anorganische und allgemeine Chemie, Wiley, Vol. 637, No. 5 ( 2011-04), p. 589-595
Abstract:
Three new cpt‐metal complexes of different topology structures were synthesized by solvothermal methods [Hcpt = 4‐(4‐carboxyphenyl)‐1,2,4‐triazole]. The structure of [Mn(cpt) 2 · 2H 2 O] ( 1 ) is essentially 0D monomeric, but extended into a 2D supramolecular network through cross‐linking hydrogen bonds. In [Cu(cpt)(OH) · 2H 2 O] · 2H 2 O ( 2 ), the hydroxo groups as well as cpt ligands join the copper ions into an infinite polymeric [Cu(μ‐cpt)(μ‐OH)] chain, which is interconnected into a 3D supramolecular network with different oriented channels by 1D water chains. The complex [Zn(cpt) 2 ] · 0.5DMF · CH 3 CH 2 OH ( 3 ), which crystallizes in a 3D open framework with fourfold interpenetrated diamondoid network topology, represents the first 3D structure based on cpt anions. The structure differences demonstrate that the reaction metal ions have an important effect on the structures of these complexes.
Type of Medium:
Online Resource
ISSN:
0044-2313
,
1521-3749
DOI:
10.1002/zaac.201000368
Language:
English
Publisher:
Wiley
Publication Date:
2011
detail.hit.zdb_id:
201094-X
detail.hit.zdb_id:
1481139-X
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