In:
Zeitschrift für anorganische und allgemeine Chemie, Wiley, Vol. 641, No. 10 ( 2015-08), p. 1808-1812
Abstract:
Abstract. The 3D cobalt(II) coordination polymers [Co 1.5 (HDDB)(1,4‐bib) 1.5 (H 2 O)] n ( 1 ), and {[Co 2 (DDB)(1,3‐bib) 2 (μ 2 ‐H 2 O)] · H 2 O} n ( 2 ) were assembled by mixed‐ligand synthetic strategy [H 4 DDB = 1,3‐bis(2,4‐dicarboxyphenyl) benzene, 1,3‐bib = 1,3‐bis(1H‐imidazol‐4‐yl)benzene, and 1,4‐bib = 1,4‐bis(1H‐imidazol‐4‐yl)benzene]. Their structures were determined by single‐crystal X‐ray diffraction analyses and further characterized by elemental analyses (EA), IR spectroscopy, powder X‐ray diffraction (PXRD), and thermogravimetric (TG) analyses. Single X‐ray diffraction analysis reveals that complex 1 is an interestingly 3D (3,3.6)‐connected (6 3 ) 4 (6 5 · 8 8 · 10 2 ) net, and complex 2 is an unprecedented dinuclear [Co 2 (COO)(μ 2 ‐H 2 O)] SBUs based 3D (3,6)‐connected (3 · 6 · 7)(3 2 · 4 3 · 5 4 · 6 3 · 7 · 8 2 ) net. Additionally, the magnetic properties of 2 were investigated.
Type of Medium:
Online Resource
ISSN:
0044-2313
,
1521-3749
DOI:
10.1002/zaac.v641.10
DOI:
10.1002/zaac.201500183
Language:
English
Publisher:
Wiley
Publication Date:
2015
detail.hit.zdb_id:
201094-X
detail.hit.zdb_id:
1481139-X
Permalink