In:
Zeitschrift für anorganische und allgemeine Chemie, Wiley, Vol. 642, No. 8 ( 2016-05), p. 618-625
Abstract:
Three silver(I) coordination polymers namely, [Ag 4 (L1) 2 (1, 4‐ndc) 2 ] n ( 1 ) {[Ag(L2)] · (1, 4‐Hndc) · H 2 O} n ( 2 ), and {[Ag(L3)(H 2 O)] · (1, 4‐Hndc)} n ( 3 ) [L1 = 1, 3‐bis(benzimidazol‐1‐ylmethyl)benzene, 1, 4‐H 2 ndc = 1, 4‐naphthalenedicarboxylic acid, L2 = 1, 3‐bis(5, 6‐dimethylbenzimidazole‐1‐ylmethyl)benzene, L3 = 1, 4‐bis(5, 6‐dimethylbenzimidazole)butane], were hydrothermally synthesized and characterized by single‐crystal X‐ray diffraction analysis, elemental analysis, IR spectroscopy, thermogravimetric and XRPD analysis. Complex 1 displays a 1D tube‐like chain, which is packed into a 3D supramolecular network by π–π stacking interactions. Complex 2 features an infinite 1D linear chain. Complex 3 contains a 1D wave‐like chain, which is extended into a 3D supramolecular network through O–H ··· O hydrogen bonding interactions. Moreover, these coordination polymers exhibit catalytic properties for degradation of methyl orange in Fenton‐like processes.
Type of Medium:
Online Resource
ISSN:
0044-2313
,
1521-3749
DOI:
10.1002/zaac.201600025
Language:
English
Publisher:
Wiley
Publication Date:
2016
detail.hit.zdb_id:
201094-X
detail.hit.zdb_id:
1481139-X
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