In:
Angewandte Chemie, Wiley, Vol. 134, No. 21 ( 2022-05-16)
Kurzfassung:
Metal‐free and metal‐containing molecular trefoil knots are fascinating ensembles that are usually covalently assembled, the latter requiring the rational design of di‐ or multidentate/multipodal ligands as connectors. In this work, we describe the self‐assembly of pentadecanuclear Au I trefoil knots [Au 15 (C≡CR) 15 ] from monoalkynes HC≡CR (R=9,9‐X 2 ‐fluorenyl with X= n Bu, n ‐hexyl) and [Au I (THT)Cl]. Hetero‐bimetallic counterparts [Au 9 M 6 (C≡CR) 15 ] (M=Cu/Ag) were self‐assembled by reactions of [Au 15 (C≡CR) 15 ] with [Cu(MeCN) 4 ] + /AgNO 3 and HC≡CR. The type of pentadecanuclear trefoil knots described herein is characterized by X‐ray crystallography, 2D NMR and HR‐ESI‐MS. [Au 9 Cu 6 (C≡CR) 15 ] is relatively stable in hexane; its excited state properties were investigated. DFT calculations revealed that non‐covalent metal–metal and metal–ligand interactions, together with longer alkyl chain‐strengthened inter‐ligand dispersion interactions, govern the stability of the trefoil knot structures.
Materialart:
Online-Ressource
ISSN:
0044-8249
,
1521-3757
DOI:
10.1002/ange.v134.21
DOI:
10.1002/ange.202200748
Sprache:
Englisch
Verlag:
Wiley
Publikationsdatum:
2022
ZDB Id:
505868-5
ZDB Id:
506609-8
ZDB Id:
514305-6
ZDB Id:
505872-7
ZDB Id:
1479266-7
ZDB Id:
505867-3
ZDB Id:
506259-7
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