In:
Angewandte Chemie, Wiley, Vol. 128, No. 8 ( 2016-02-18), p. 2890-2894
Abstract:
The first example of iron‐catalyzed decarboxylative (4+1) cycloaddition reactions is described in this publication. By using this method, a wide range of functionalized indoline products were prepared from easily available vinyl benzoxazinanones and sulfur ylides in high yields and selectivities. A possible reaction pathway involving an allylic iron intermediate is discussed based on a series of control experiments and density‐functional theory calculations.
Type of Medium:
Online Resource
ISSN:
0044-8249
,
1521-3757
DOI:
10.1002/ange.201510413
Language:
English
Publisher:
Wiley
Publication Date:
2016
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505868-5
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514305-6
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505872-7
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1479266-7
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505867-3
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506259-7
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