In:
Angewandte Chemie, Wiley, Vol. 130, No. 28 ( 2018-07-09), p. 8629-8633
Abstract:
The graft‐through synthesis of Janus graft block copolymers (GBCPs) from branched macromonomers composed of various combinations of homopolymers is presented. Self‐assembly of GBCPs resulted in ordered nanostructures with ultra‐small domain sizes down to 2.8 nm (half‐pitch). The grafted architecture introduces an additional parameter, the backbone length, which enables control over the thermomechanical properties and processability of the GBCPs independently of their self‐assembled nanostructures. The simple synthetic route to GBCPs and the possibility of using a variety of polymer combinations contribute to the universality of this technique.
Type of Medium:
Online Resource
ISSN:
0044-8249
,
1521-3757
DOI:
10.1002/ange.v130.28
DOI:
10.1002/ange.201802844
Language:
English
Publisher:
Wiley
Publication Date:
2018
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505872-7
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1479266-7
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