In:
Zeitschrift für anorganische und allgemeine Chemie, Wiley, Vol. 647, No. 11 ( 2021-06-11), p. 1198-1202
Abstract:
A new 3D porous Zn(II) compound [Zn 2 (L) 2 (C 2 O 4 )] n ⋅ 2(DMA) ( 1 , HL=4‐(4‐carboxyphenyl)‐2,2′ : 4′,4′′‐terpyridine, DMA=N, N’‐dimethylacetamide) was successfully synthesized with carboxyphenyl‐terpyridine ligand. X‐ray structural analysis revealed that compound 1 features a 2‐fold interpenetrated framework with (3,4)‐connected network topology. Despite interpenetration, compound 1 still contains high solvent‐accessible free volume owing to the existence of large 1D nanotube channels. Gas adsorption properties investigation of the activated 1 a confirms its high BET surface area, high CO 2 uptake capacity and excellent adsorption selectivity of CO 2 over CH 4 . Luminescent properties investigation indicate that compound 1 displays intense luminescence at room temperature.
Type of Medium:
Online Resource
ISSN:
0044-2313
,
1521-3749
DOI:
10.1002/zaac.v647.11
DOI:
10.1002/zaac.202000457
Language:
English
Publisher:
Wiley
Publication Date:
2021
detail.hit.zdb_id:
201094-X
detail.hit.zdb_id:
1481139-X
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