In:
European Journal of Organic Chemistry, Wiley, Vol. 2018, No. 45 ( 2018-12-06), p. 6199-6203
Abstract:
As a first non‐metal‐catalyzed oxidation for the in situ generation of acylnitroso species, we describe the hypoiodite catalysis using tetra‐ n ‐butylammonium iodide as precatalyst with tert ‐butyl hydroperoxide or hydrogen peroxide as a terminal oxidant. This method can be applied to hetero Diels–Alder (HDA) reactions with dienes and ene reactions with alkenes. Furthermore, the conversions of the representative HDA adduct to nitrone and 2‐amino alcohols were demonstrated. Compared with previous metal‐catalyzed oxidation methods, this work provides a more efficient and environmentally friendly procedure.
Type of Medium:
Online Resource
ISSN:
1434-193X
,
1099-0690
DOI:
10.1002/ejoc.v2018.45
DOI:
10.1002/ejoc.201801340
Language:
English
Publisher:
Wiley
Publication Date:
2018
detail.hit.zdb_id:
1475010-7
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