In:
Chemistry Letters, Oxford University Press (OUP), Vol. 22, No. 10 ( 1993-10-01), p. 1799-1802
Abstract:
3-Acetamido-6-heptafluoropropylphenylboronic acid was synthesized by the perfluoroalkylation of 3-acetamidophenylboronic acid (pKa = 8.3) with bis(heptafluorobutyryl)peroxide. The perfluoroalkylated phenylboronic acid thus prepared was determined to have a low pKa as 6.6 by potentiometric titration. Lowered pKa suggests that the product has an advantage for binding with polyols under physiological pH, opening a wide application in the field of biological as well as material sciences.
Type of Medium:
Online Resource
ISSN:
0366-7022
,
1348-0715
DOI:
10.1246/cl.1993.1799
Language:
English
Publisher:
Oxford University Press (OUP)
Publication Date:
1993
detail.hit.zdb_id:
2063626-X
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