In:
European Journal of Organic Chemistry, Wiley, Vol. 2005, No. 15 ( 2005-08), p. 3196-3205
Abstract:
New types of di‐ and trisaccharides related to a unique trisaccharide present in the cell walls of Proteus have been synthesized by coupling of acyclic sugar dithioacetals and di‐ and monohydroxy cyclic sugars. In this class of compounds an acyclic sugar is linked to a cyclic sugar through an acetal linkage. The formation of these acetal‐linked pseudodi‐ and‐trisaccharides has been achieved by a generalized reaction procedure mediated by 1,3‐dibromo‐5,5‐dimethylhydantoin under mild, metal‐free and neutral conditions. Sixteen protected and twelve deprotected di‐ and trisaccharides related to the trisaccharide found in the Proteus cell wall have been synthesized. (© Wiley‐VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2005)
Type of Medium:
Online Resource
ISSN:
1434-193X
,
1099-0690
DOI:
10.1002/ejoc.v2005:15
DOI:
10.1002/ejoc.200500081
Language:
English
Publisher:
Wiley
Publication Date:
2005
detail.hit.zdb_id:
1475010-7
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