In:
Zeitschrift für anorganische und allgemeine Chemie, Wiley, Vol. 641, No. 6 ( 2015-05), p. 1114-1118
Abstract:
Hydrothermal reactions of biphenyl‐2,3,3′,5′‐tetracarboxylic acid (H 4 bptc) with zinc salts in the presence of 1,4‐bis(2‐pyridylmethyl)piperazin (bpmp) and 4,4‐dipyridyl (dpy) afforded the coordination polymers {[Zn 2 (bptc)(bpmp)] · 3H 2 O} n ( 1 ) and {[Zn(H 2 bptc)(dpy)] · 3H 2 O} n ( 2 ). Their structures were determined by single‐crystal X‐ray diffraction analysis and further characterized by elemental analysis, IR spectroscopy, and TG analyses. Complex 1 displays an unusual three‐dimensional (3D) supramolecular motif generated by hydrogen bonding interactions between two single‐layered 2D networks. Complex 2 represents a 2D layer structure, and such layers are further united together into three‐dimensional supramolecular structure through intricate hydrogen bonding. In addition, luminescence properties of complexes 1 and 2 were also investigated.
Type of Medium:
Online Resource
ISSN:
0044-2313
,
1521-3749
DOI:
10.1002/zaac.201400483
Language:
English
Publisher:
Wiley
Publication Date:
2015
detail.hit.zdb_id:
201094-X
detail.hit.zdb_id:
1481139-X
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