In:
Angewandte Chemie, Wiley, Vol. 127, No. 42 ( 2015-10-12), p. 12581-12586
Abstract:
We report the evaporation of a stable cyclic silylene and its oxidation (with ozone or N 2 O) through oxygen atom transfer to form the corresponding silanone under matrix isolation conditions. As uncomplexed silanones are rare owing to their very high reactivity, this method provides an alternative route to these sought‐after molecules. The silanone, as well as a novel bicyclic silane with a bridgehead silicon atom derived from an intramolecular silylene CH bond insertion, were characterized by comparison of high‐resolution infrared spectra with density functional theory (DFT) computations at the M06‐2X/cc‐pVDZ level of theory.
Type of Medium:
Online Resource
ISSN:
0044-8249
,
1521-3757
DOI:
10.1002/ange.v127.42
DOI:
10.1002/ange.201501844
Language:
English
Publisher:
Wiley
Publication Date:
2015
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505872-7
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