In:
Angewandte Chemie, Wiley, Vol. 132, No. 10 ( 2020-03-02), p. 3868-3873
Abstract:
Ordered and flexible porous frameworks with solution processability are highly desirable to fabricate continuous and large‐scale membranes for the efficient gas separation. Herein, the first microporous hydrogen‐bonded organic framework (HOF) membrane has been fabricated by an optimized solution‐processing technique. The framework exhibits the superior stability because of the abundant hydrogen bonds and strong π–π interactions. Thanks to the flexible HOF structure, the membrane possesses the unprecedented pressure‐responsive H 2 /N 2 separation performance. Furthermore, the scratched membrane can be healed by the treatment of solvent vapor, achieving the recovery of separation performance.
Type of Medium:
Online Resource
ISSN:
0044-8249
,
1521-3757
DOI:
10.1002/ange.v132.10
DOI:
10.1002/ange.201914548
Language:
English
Publisher:
Wiley
Publication Date:
2020
detail.hit.zdb_id:
505868-5
detail.hit.zdb_id:
506609-8
detail.hit.zdb_id:
514305-6
detail.hit.zdb_id:
505872-7
detail.hit.zdb_id:
1479266-7
detail.hit.zdb_id:
505867-3
detail.hit.zdb_id:
506259-7
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