In:
Angewandte Chemie, Wiley, Vol. 132, No. 2 ( 2020-01-07), p. 768-772
Abstract:
Electrochemical reduction of CO 2 into various chemicals and fuels provides an attractive pathway for environmental and energy sustainability. It is now shown that a FeP nanoarray on Ti mesh (FeP NA/TM) acts as an efficient 3D catalyst electrode for the CO 2 reduction reaction to convert CO 2 into alcohols with high selectivity. In 0.5 m KHCO 3 , such FeP NA/TM is capable of achieving a high Faradaic efficiency (FE ) up to 80.2 %, with a total FE of 94.3 % at −0.20 V vs. reversible hydrogen electrode. Density functional theory calculations reveal that the FeP(211) surface significantly promotes the adsorption and reduction of CO 2 toward CH 3 OH owing to the synergistic effect of two adjacent Fe atoms, and the potential‐determining step is the hydrogenation process of *CO.
Type of Medium:
Online Resource
ISSN:
0044-8249
,
1521-3757
DOI:
10.1002/ange.201912836
Language:
English
Publisher:
Wiley
Publication Date:
2020
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514305-6
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505872-7
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1479266-7
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506259-7
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