In:
Zeitschrift für Naturforschung B, Walter de Gruyter GmbH, Vol. 45, No. 6 ( 1990-6-1), p. 833-847
Abstract:
Reactions of β-chlorovinylcarbonyl compounds 10, 14, 16, 18, 20, 22, with sodium dicarbonyl-η 5 -cyclopentadienyl-ferrate (NaFp) furnish β-acylvinyl-dicarbonyl-η 5 -cyclopentadienyliron complexes 15, 17, 19, 21, 23 and binuclear iron complexes 26-29. Spectral data demonstrate the donor effect of the Fp group. Irradiation of these complexes in the presence of triphenylphosphane delivers β-acylvinyl-carbonyl-η 5 -cyclopentadienyl-triphenylphosphane-iron complexes 34, 35. Reaction of glutarimides with oxalyl chloride gives rise to oxazolo-[3,2 a]pyridines 13. Benzylidenemalonyl chloride reacts with FpCS 2 Na to form benzylidenethietane-2,4-dione (32). A β-acylethinyl-carbonyl-η 5 -dicyclopentadienyl-iron complex 43 has been prepared.
Type of Medium:
Online Resource
ISSN:
1865-7117
,
0932-0776
DOI:
10.1515/znb-1990-0615
Language:
English
Publisher:
Walter de Gruyter GmbH
Publication Date:
1990
detail.hit.zdb_id:
2078109-X
detail.hit.zdb_id:
124635-5
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