In:
Canadian Journal of Chemistry, Canadian Science Publishing, Vol. 63, No. 11 ( 1985-11-01), p. 3233-3241
Abstract:
A synthesis of dimethyl tetracyclo[5.2.1.0 2,6 .0 3,8 ]decane-7,8-dicarboxylate, 3, w hose key step implies the formation of the C1—C2 bond by regioselective intramolecular C—H insertion of a carbene generated from dimethyl (1R,2S,6R,7S)-10-oxotricyclo[5.2.1.0 2,6 ]decane-2,6-dicarboxylate, 1 via its tosylhydrazone, is described. Attempts to synthesize diester 3 or compounds containing its carbon skeleton, by forming the same C—C bond, starting from dimethyl (1R,2S,6R,7S)-4-oxotricyclo[5.2.1.0 2,6 ]decane-2,6-dicarboxylate, 2, or the corresponding anhydride, 13, are also included.
Type of Medium:
Online Resource
ISSN:
0008-4042
,
1480-3291
Language:
English
Publisher:
Canadian Science Publishing
Publication Date:
1985
detail.hit.zdb_id:
1482256-8
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