In:
Angewandte Chemie, Wiley, Vol. 128, No. 34 ( 2016-08-16), p. 10086-10090
Abstract:
To combine flexibility and modifiability towards a more controllable complexity of MOFs, a post‐synthetic variable‐spacer installation (PVSI) strategy is used to implement kinetic installation/ uninstallation of secondary ligands into/from a robust yet flexible proto‐Zr‐MOF. This PVSI process features precise positioning of spacers with different length, size, number, and functionality, enabling accurate fixation of successive breathing stages and fine‐tuning of pore surface. It shows unprecedented synthetic tailorability to create complicated MOFs in a predictable way for property modification, for example, CO 2 and R22 adsorption/separation, thermal/chemical stability, and extended breathing behavior.
Type of Medium:
Online Resource
ISSN:
0044-8249
,
1521-3757
DOI:
10.1002/ange.v128.34
DOI:
10.1002/ange.201604023
Language:
English
Publisher:
Wiley
Publication Date:
2016
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505868-5
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514305-6
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505872-7
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1479266-7
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506259-7
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