In:
Chemistry – A European Journal, Wiley, Vol. 21, No. 35 ( 2015-08-24), p. 12299-12302
Abstract:
Dioxygen is used as the oxygenation agent in the rhodium‐mediated conversion of nitriles into amides. The characterization of intermediate species and model compounds as well as isotope‐labeling studies provided an insight into the reaction mechanism. The conversions of rhodium hydroperoxido or methylperoxido complexes with nitriles into metallacyclic rhodium‐ κ 2 ‐( N , O )‐peroxyimidate compounds represent essential key steps. The former are accessible from a rhodium(III) peroxido complex and the latter represent rhodium derivatives of Payne’s reagent (peroxyimidic acids).
Type of Medium:
Online Resource
ISSN:
0947-6539
,
1521-3765
DOI:
10.1002/chem.201502481
Language:
English
Publisher:
Wiley
Publication Date:
2015
detail.hit.zdb_id:
1478547-X
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