In:
Chemistry – A European Journal, Wiley, Vol. 27, No. 61 ( 2021-11-02), p. 15209-15217
Abstract:
Nucleophilic substitution of [(η 5 ‐cyclopentadienyl)(η 6 ‐chlorobenzene)iron(II)] hexafluorophosphate with sodium imidazolate resulted in the formation of [(η 5 ‐cyclopentadienyl)(η 6 ‐phenyl)iron(II)]imidazole hexafluorophosphate. The corresponding dicationic imidazolium salt, which was obtained by treating this imidazole precursor with methyl iodide, underwent cyclometallation with bis[dichlorido(η 5 ‐1,2,3,4,5‐pentamethylcyclopentadienyl]iridium(III) in the presence of triethyl amine. The resulting bimetallic iridium(III) complex is the first example of an NHC complex bearing a cationic and cyclometallated [(η 5 ‐cyclopentadienyl)(η 6 ‐phenyl)iron(II)] + substituent. As its iron(II) precursors, the bimetallic iridium(III) complex was fully characterized by means of spectroscopy, elemental analysis and single crystal X‐ray diffraction. In addition, it was investigated in a catalytic study, wherein it showed high activity in transfer hydrogenation compared to its neutral analogue having a simple phenyl instead of a cationic [(η 5 ‐cyclopentadienyl)(η 6 ‐phenyl)iron(II)] + unit at the NHC ligand.
Type of Medium:
Online Resource
ISSN:
0947-6539
,
1521-3765
DOI:
10.1002/chem.202102520
Language:
English
Publisher:
Wiley
Publication Date:
2021
detail.hit.zdb_id:
1478547-X
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