In:
Chemistry – A European Journal, Wiley, Vol. 20, No. 51 ( 2014-12-15), p. 16858-16862
Abstract:
The nickel‐catalyzed direct carboxylation of alkenes with the cheap and abundantly available C 1 building block carbon dioxide (CO 2 ) in the presence of a base has been achieved. The one‐pot reaction allows for the direct and selective synthesis of a wide range of α,β‐unsaturated carboxylates (TON 〉 100, TOF up to 6 h −1 , TON=turnover number, TOF=turnover frequency). Thus, it is possible, in one step, to synthesize sodium acrylate from ethylene, CO 2 , and a sodium salt. Acrylates are industrially important products, the synthesis of which has hitherto required multiple steps.
Type of Medium:
Online Resource
ISSN:
0947-6539
,
1521-3765
DOI:
10.1002/chem.201405528
Language:
English
Publisher:
Wiley
Publication Date:
2014
detail.hit.zdb_id:
1478547-X
detail.hit.zdb_id:
1231884-X
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