In:
Zeitschrift für Naturforschung B, Walter de Gruyter GmbH, Vol. 35, No. 10 ( 1980-10-1), p. 1254-1256
Abstract:
Bis(η 5 -cyclopentadienyl)N,N-disubstituted dithiocarbamato(chloro)oxomolybdenum(VI) complexes of the type (C 5 H 5 ) 2 MoO(S 2 CNR 2 )Cl and (C 5 H 5 ) 2 MoO(S 2 CNRR′)Cl where R = Me, Et, i-Pr and R′ = cyclohexyl (cyhx) have been prepared by the reaction of stoichiometric amounts of bis(η 5 -cyclopentadienyl)oxomolybderium(VI) dichloride with sodium dithiocarbamates in refluxing dichloromethane. Infrared spectral studies demonstrate that in these complexes, the dithiocarbamate ligands are bidentate. Hence a coordination number of 7 may be assigned to the molybdenum(VI) atom in each case. In addition to infrared studies, electronic spectra, NMR studies, magnetic susceptibility, elemental analyses and conductance measurements have been carried out for these complexes.
Type of Medium:
Online Resource
ISSN:
1865-7117
,
0932-0776
DOI:
10.1515/znb-1980-1016
Language:
English
Publisher:
Walter de Gruyter GmbH
Publication Date:
1980
detail.hit.zdb_id:
2078109-X
detail.hit.zdb_id:
124635-5
Permalink