Description: Analyses of the chemical and isotopic composition of carbonates rocks recovered from methane seepage areas of the Kodiak Trench, Hydrate Ridge, Monterey Bay Clam Flats, and the Eel River Basin, coupled with the studies of the chemistry of the pore fluids, have shown that these carbonates have grown within the sediment column. Geochemical profiles of pore fluids show that, in deep water seeps (Kodiak Trench—4450 m; Monterey Bay—1000 m; Hydrate Ridge—650 m), δ13C (DIC) values are low (isotopically light), whereas in the Eel River area (∼ 350–500 m), δ13C (DIC) values are much higher (isotopically heavier). In all cases, the δ13C values indicate that processes of methane oxidation, associated with sulfate reduction, are dominant in the shallow sediments. Data on the isotopic composition of authigenic carbonates found at sites in Kodiak Trench, Eel River Basin South, and Eel River Basin North indicate a variable composition and origin in different geochemical environments. Some of the authigenic carbonates from the study sites show a trend in their δ13C values similar to those of the pore fluids obtained in their vicinity, suggesting formation at relatively shallow depths, but others indicate formation at greater sediment depths. The latter usually consist of high magnesium calcite or dolomite, which, from their high values of δ13C (up to 23‰;) and δ18O (up to 7.5‰), suggest formation in the deeper horizons of the sediments, in the zone of methanogenesis. These observations are in agreement with observations by other workers at Hydrate Ridge, in Monterey Bay, and in the Eel River Basin.

Description: Proglacial streams deliver melt water and chemical weathering products, including nutrients and radiogenic isotopes, from continental ice sheets to the ocean. Weathering products are also delivered to the ocean in non-glacial streams that form following ice sheet retreat and are disconnected from ice sheet meltwater by hydrologic divides. If weathering reactions differ in non-glacial and proglacial stream catchments, the streams could deliver different types and magnitudes of solutes to the ocean, depending on relative discharge volumes. Unlike proglacial streams, however, little is known of non-glacial stream solute compositions or discharge. Here we show specific discharges are similar from a proglacial stream draining the Greenland Ice Sheet (GrIS) with several streams disconnected from the ice sheet. We also evaluate weathering reactions across a 170-km transect in western Greenland that contains one proglacial stream draining the GrIS, and two coastal (ice distal) and three inland (ice proximal) areas with non-glacial streams. Non-glacial streams exhibit solute compositions and offsets between dissolved and bedload Sr isotope ratios that indicate weathering increases toward the coast with exposure age and precipitation. Major element mass balance calculations show weathering reactions shift from predominately carbonic acid weathering of carbonate minerals inland near the ice sheet to predominately sulfuric acid weathering of carbonate minerals near the coast. Strontium concentrations and isotopic ratios of the proglacial stream reflect mixing of at least two subglacial sources and minor in-stream weathering that consumes CO2. About 5 times less CO2 is consumed per liter in the proglacial than inland non-glacial streams; however, arid conditions inland suggest limited discharge from the ungauged inland streams leads to less total CO2 weathering than proglacial stream. One coastal area consumes less CO2 per liter than the proglacial stream and another coastal area exhibits net CO2 production. These results indicate estimates for glacial foreland solute fluxes and CO2 weathering consumption and production should include estimates from both non-glacial and proglacial streams. Understanding weathering fluxes from these two types of streams will be important for evaluations of past ice sheet retreat and predictions of future solute and CO2 fluxes associated with continued ice sheet retreat.