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  • 1
    Publication Date: 2023-01-27
    Description: Abrupt fluid emissions from shallow marine sediments pose a threat to seafloor installations like wind farms and offshore cables. Quantifying such fluid emissions and linking pockmarks, the seafloor manifestations of fluid escape, to flow in the sub‐seafloor remains notoriously difficult due to an incomplete understanding of the underlying physical processes. Here, using a compositional multi‐phase flow model, we test plausible gas sources for pockmarks in the south‐eastern North Sea, which recent observations suggest have formed in response to major storms. We find that the mobilization of pre‐existing gas pockets is unlikely because free gas, due to its high compressibility, damps the propagation of storm‐induced pressure changes deeper into the subsurface. Rather, our results point to spontaneous appearance of a free gas phase via storm‐induced gas exsolution from pore fluids. This mechanism is primarily driven by the pressure‐sensitivity of gas solubility, and the appearance of free gas is largely confined to sediments in the vicinity of the seafloor. We show that in highly permeable sediments containing gas‐rich pore fluids, wave‐induced pressure changes result in the appearance of a persistent gas phase. This suggests that seafloor fluid escape structures are not always proxies for overpressured shallow gas and that periodic seafloor pressure changes can induce persistent free gas phase to spontaneously appear.
    Description: Plain Language Summary: Thousands of pockmarks, circular depressions in the seafloor, were reported in North Sea, presumably formed in response to wave motions during major storms. It has been hypothesized that these pockmarks formed as pre‐existing shallow free‐gas pockets were mobilized by pressure changes of the waves. However, mechanisms that could have mobilized free‐gas are not yet constrained. Moreover, large scale free‐gas accumulations have not been reported in this region, and therefore, commonly invoked mechanisms like tensile failure and breaching of capillary seals are hard to justify as they rely on the presence of pre‐existing gas pockets. Here, through modeling studies, we tackle the question of the source of the observed free‐gas. Our study consists of two parts: First, assuming that some hitherto unknown shallow free‐gas pocket is indeed present, we test whether storm‐induced pressure changes could breach capillary seals. We find that free‐gas damps pressure changes due to its high compressibility, making the mobilization of pre‐existing gas unlikely. In the second part, we propose an alternative mechanism where free‐gas spontaneously appears due to exsolution from pore‐fluids. We test the feasibility of this mechanism and show how periodic pressure changes can lead to a persistent gas phase, that could explain the elusive gas source linked to these pockmarks.
    Description: Key Points: Storm‐induced pressure changes can lead to spontaneous appearance of free gas phase near the seafloor. This process is driven by pressure‐sensitive phase instabilities. This mechanism could help explain elusive gas sources in recently observed pockmarks in the North Sea.
    Description: Aker BP (AkerBP) http://dx.doi.org/10.13039/100016998
    Description: Deutsche Forschungsgemeinschaft, DFG
    Keywords: ddc:550 ; pockmarks ; storm related pockmarks ; spontaneous free gas ; gas source ; modeling
    Language: English
    Type: doc-type:article
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  • 2
    Publication Date: 2023-01-20
    Description: Gross gains and losses of stream water and the consequent hydrologic turnover may modify the composition of stream water and drive in‐stream ecological functioning. We evaluated over 500 breakthrough curves of conservative tracer additions to analyze the channel water balance resulting in gross gains and losses, net exchange, and hydrologic turnover. During the hydrological year 2019, seven tracer experiments had been carried out in six first‐order streams along 400 m study reaches. All streams are located in the Holtemme catchment (Central Germany) with three each dominated by forested and agricultural land use. Four of the six streams were characterized by net‐losing conditions. The overall median of gross exchange was five times higher than net exchange. On average, subsurface gains replaced 50% of the original stream water over less than one kilometer of stream length. We even observed cases where over 95% of the stream water turned over within 100 m. Gross exchange was relatively higher in forested than in agricultural streams. Patterns of exchange in the forested streams persisted spatially and were temporally independent of streamflow, whereas in the agricultural ones, variable spatial patterns and streamflow dependence occurred. Overall, moderate flow coincided with highest relative gross exchange. Our results support previous findings that in‐stream solute concentrations could heavily depend on location and magnitude of gains and losses. Gross exchange embodies a permanent but variable control of downstream solute concentrations interacting with the signal of biogeochemical activity. We highlight the importance to include reach‐scale hydrological processes in studies on nutrient spiraling.
    Description: Plain Language Summary: The vitality of stream ecosystems largely relies on the exchange of water between surface and groundwater. This comprises all gains and losses of stream water from and to the subsurface and is referred to as gross exchange. We investigated gross exchange for six headwater streams in the Holtemme catchment (Central Germany) during the hydrological year 2019. By applying salt tracer experiments we calculated the extent of exchange. Consistently, the investigated stream reaches lost more water than they gained. On average, half of the stream water was replaced by newly added groundwater along less than one km of stream length and, in few cases, almost the entire volume was exchanged within 100 m distance. Streams surrounded by forest exchanged more water than streams in agricultural landscapes. The location and direction of exchange remained similar in the forested streams, but varied temporarily for the agricultural streams. We could show that groundwater represents an important volume of our streams and that the true gross exchange can easily be underestimated if only the sum of gains and losses is measured. Therefore, solute concentrations can be strongly modified by gross exchange, which is important to better understand the transport of solutes in streams.
    Description: Key Points: In over 90% of the cases, gross exchange equals five times the net exchange, which impacts interpretations of nutrient uptake. Gross exchange and hydrologic turnover show spatiotemporal patterns persisting over discharge at forested, but not at agricultural sites. Moderate discharge exhibits the highest relative gross exchange.
    Keywords: ddc:551.48 ; gross gain and loss ; hydrologic turnover ; headwater streams ; reach scale ; losing streams ; land use
    Language: English
    Type: doc-type:article
    Location Call Number Limitation Availability
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