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  • 1
    Electronic Resource
    Electronic Resource
    Oxford, UK : Blackwell Publishing Ltd
    Community dentistry and oral epidemiology 25 (1997), S. 0 
    ISSN: 1600-0528
    Source: Blackwell Publishing Journal Backfiles 1879-2005
    Topics: Medicine
    Notes: Abstract The study presents the results of a preventive program based on a children's book and carried out in the elementary schools of Bergamo, Italy. The book was published to improve 8-year-old schoolchildren's knowledge of primary dentition, dental plaque, nutrition, oral hygiene, fluoride and regular dental visits. The study was experimental. A total of 440 schoolchildren were selected to test the effectiveness of the book. They were divided into four groups: two groups underwent the training program and the other two were control groups. Measurements were made using the Quigley-Hein index before and after the program. A significant difference reduction of the plaque index of –0.6 was observed (P〈0.005).
    Type of Medium: Electronic Resource
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  • 2
    Electronic Resource
    Electronic Resource
    Oxford, UK : Blackwell Publishing Ltd
    Journal of food science 45 (1980), S. 0 
    ISSN: 1750-3841
    Source: Blackwell Publishing Journal Backfiles 1879-2005
    Topics: Agriculture, Forestry, Horticulture, Fishery, Domestic Science, Nutrition , Process Engineering, Biotechnology, Nutrition Technology
    Notes: The characteristics of mango (Mangifera indica var. Haden) polyphenol oxidase (PPO) extract were investigated in order to use it in mango processing. The optimum pH of the enzyme was 5.6–6.0, which is unusual as compared to other fruits. For heat inactivation, half-activity of the enzyme was lost after 2.1 and 4.0 mm of treatment at 85 and 80°C, respectively. Regarding the effect of inhibitors on the enzyme, sodium metabisulfite was the most effective, while ascorbic acid was the least. Polyacrylamide gel electrophoresis revealed two isoenzymes which moved toward the anode at pH 8.6 as detected with catechol as substrate; no bands were observed when L-tyrosine was used as substrate. It was found that electrophoretic patterns of mango PPO were quite different, compared to other plant PPO systems.
    Type of Medium: Electronic Resource
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  • 3
    Publication Date: 2012-05-01
    Description: Raman spectroscopy can measure water concentrations of hydrous silicate glasses with several advantages such as: (1) high-spatial resolution of 1–2 μm2; (2) non-destructive character; and (3) easy access, without any specific sample preparation or mounting techniques. The latter reasons render Raman highly suitable for studying natural products, such as volcanic pumice and scoriae fragments. Two spectral regions can be distinguished in Raman spectra of hydrated silicate glasses: a low-wavenumber region (15–1500 cm−1), which corresponds to vibrations of the silicate network, and a high-wavenumber region (3100–3750 cm−1), corresponding to the OH stretching vibrations of H2O molecules and OH groups. Behrens et al. (2006) have published empirical equations relating the area ratio between these two regions and the water content. However, the proposed internal calibrations depend on chemical composition of the glasses. In this paper, we reinvestigated the previous procedures to improve the background subtraction. Our results allow us to present a more general and linear calibration. Water concentrations up to 13 wt% can be measured for a broad range of natural silicate melts, from basalts to rhyolite (40 up to 80 wt% SiO2), using a single calibration curve with an absolute error of 0.2 wt%.
    Print ISSN: 0003-004X
    Electronic ISSN: 1945-3027
    Topics: Geosciences
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  • 4
    Publication Date: 2016-11-04
    Description: Steam-driven eruptions, both phreatic and hydrothermal, expel exclusively fragments of non-juvenile rocks disintegrated by the expansion of water as liquid or gas phase. As their violence is related to the magnitude of the decompression work that can be performed by fluid expansion, these eruptions may occur with variable degrees of explosivity. In this study we investigate the influence of liquid fraction and rock petrophysical properties on the steam-driven explosive energy. A series of fine-grained heterogeneous tuffs from the Campi Flegrei caldera were investigated for their petrophysical properties. The rapid depressurization of various amounts of liquid water within the rock pore space can yield highly variable fragmentation and ejection behaviors for the investigated tuffs. Our results suggest that the pore liquid fraction controls the stored explosive energy with an increasing liquid fraction within the pore space increasing the explosive energy. Overall, the energy released by steam flashing can be estimated to be one order of magnitude higher than for simple (Argon) gas expansion, and may produce a higher amount of fine material even under partially-saturated conditions. The energy surplus in the presence of steam flashing leads to a faster fragmentation with respect to gas-expansion, and in to higher ejection velocities imparted to the fragmented particles. Moreover, weak and low permeability rocks yield a maximum fine fraction. Using experiments to unravel the energetics of steam-driven eruptions has yielded estimates for several parameters controlling their explosivity. These findings should be considered for both modeling and evaluation of the hazards associated with steam-driven eruptions.
    Print ISSN: 0148-0227
    Topics: Geosciences , Physics
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  • 5
    Publication Date: 2020-11-25
    Description: Over the past two decades, La Soufrière volcano in Guadeloupe has displayed a growing degassing unrest whose actual source mechanism still remains unclear. Based on new measurements of the chemistry and mass flux of fumarolic gas emissions from the volcano, here we reveal spatio-temporal variations in the degassing features that closely relate to the 3D underground circulation of fumarolic fluids, as imaged by electrical resistivity tomography, and to geodetic-seismic signals recorded over the past two decades. Discrete monthly surveys of gas plumes from the various vents on La Soufrière lava dome, performed with portable MultiGAS analyzers, reveal important differences in the chemical proportions and fluxes of H2O, CO2, H2S, SO2 and H2, which depend on the vent location with respect to the underground circulation of fluids. In particular, the main central vents, though directly connected to the volcano conduit and preferentially surveyed in past decades, display much higher CO2/SO2 and H2S/SO2 ratios than peripheral gas emissions, reflecting greater SO2 scrubbing in the boiling hydrothermal water at 80–100 m depth. Gas fluxes demonstrate an increased bulk degassing of the volcano over the past 10 years, but also a recent spatial shift in fumarolic degassing intensity from the center of the lava dome towards its SE–NE sector and the Breislack fracture. Such a spatial shift is in agreement with both extensometric and seismic evidence of fault widening in this sector due to slow gravitational sliding of the southern dome sector. Our study thus provides an improved framework to monitor and interpret the evolution of gas emissions from La Soufrière in the future and to better forecast hazards from this dangerous andesitic volcano.
    Description: Published
    Description: id 480
    Description: 4V. Processi pre-eruttivi
    Description: JCR Journal
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Type: article
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  • 6
    Publication Date: 2021-01-05
    Description: Induced seismicity can be associated to the activity of fluid withdrawal and injection from/into the shallow crust (fracking, wastewater disposal into the deep crust, Enhanced Geothermal Systems technology, fluid extraction in oil fields and geothermal power plants). Long-term injection of large volumes of fluids is normally associated with induced seismicity, but the effect of withdrawal-reinjection in the same reservoir is less known, at least regarding its relation to simple injection. However, it is common experience worldwide that small (i.e. 10 MW or less) geothermal plants with withdrawal and re-injection of fluids in the same reservoir are mostly not associated with significant induced/triggered seismicity. This paper aims at understanding how to discriminate, on a numerical modelling basis, the seismogenic potential of withdrawal-reinjection with respect to injection only. With this aim, we analysed the induced pressure changes, the perturbed volumes of rocks and the potential for induced seismicity due to these operations. A set of simulations of injection or withdrawal-reinjection cycles, obtained by using the numerical code TOUGH2®, is applied to simple models of geothermal reservoirs, with varying permeability and lateral boundary constraints. For each permeability model, we then compare the time growth of perturbed volumes obtained with withdrawal-reinjection cycles to those obtained during simple injection, using the same flow rates. The size of perturbed volumes is then related to the maximum magnitude of induced/triggered seismicity, using models accredited in recent literature. Our results show that, for all models, withdrawal-reinjection is by far less critical than simple injection, because the perturbed volumes are remarkably smaller and remain constant over the simulated time, so minimizing the likelihood of interference with seismogenic faults. These results have significant implications for geothermal projects, and in the assessment of the potential risk related to fluid stimulation and induced seismicity.
    Description: Published
    Description: 101770
    Description: 1TR. Georisorse
    Description: JCR Journal
    Keywords: geothermal energy ; geothermal energy
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Type: article
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  • 7
    Publication Date: 2021-02-10
    Description: Ischia, one active volcano of the Phlegraean Volcanic District, prone to very high risk, is dominated by a caldera formed 55 ka BP, followed by resurgence of the collapsed area. Over the past 3 ka, the activity extruded evolved potassic magmas; only a few low-energy explosive events were fed by less evolved magmas. A geochemical and Sr–Nd–O isotope investigation has been performed on minerals and glass from products of three of such eruptions, Molara, Vateliero, and Cava Nocelle (\2.6 ka BP). Data document strong mineralogical, geochemical, and isotopic heterogeneities likely resulting from mingling/ mixing processes among mafic and felsic magmas that already fed the Ischia volcanism in the past. Detailed study on the most mafic magma has permitted to investigate its origin. The mantle sector below Ischia underwent subduction processes that modified its pristine chemical, isotopic, and redox conditions by addition of B1 % of sediment fluids/melts. Similar processes occurred from Southeast to Northwest along the Apennine compressive margin, with addition of up to 2.5 % of sediment-derived material. This is shown by volcanics with poorly variable, typical d18O mantle values, and 87Sr/86Sr progressively increasing toward typical continental crust values. Multiple partial melting of this modified mantle generated distinct primary magmas that occasionally assimilated continental crust, acquiring more 18O than 87Sr. At Ischia, 7 % of Hercynian granodiorite assimilation produced isotopically distinct, K-basaltic to latitic magmas. A SW–NE regional tectonic structure gave these magmas coming from large depth the opportunity to mingle/mix with felsic magmas stagnating in shallower reservoirs, eventually triggering explosive eruptions.
    Description: Published
    Description: 1173 - 1194
    Description: 2V. Struttura e sistema di alimentazione dei vulcani
    Description: 3V. Proprietà chimico-fisiche dei magmi e dei prodotti vulcanici
    Description: 4V. Processi pre-eruttivi
    Description: 6A. Geochimica per l'ambiente e geologia medica
    Description: JCR Journal
    Keywords: Ischia ; Mineral chemistry ; Mingling/mixing ; Mantle enrichment/ ; crustal contamination ; Oxidizing fluids
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Type: article
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  • 8
    Publication Date: 2021-05-12
    Description: Persistent degassing of closed-conduit explosive volcanoes may be used to inspect and monitor magmatic processes. After interaction with shallow hydrothermal fluids, volcanic gases collected at surface can differ substantially from those exsolved from magma. We report here on an innovative approach to identify and separate the contribution of variable magmatic components from fumarolic gases, by processing the 30-year-long geochemical dataset from the Campi Flegrei caldera, Southern Italy. The geochemical record shows periodic variations, which are well correlated with geophysical signals. Such variations are interpreted as due to the time-varying interplay of two magma degassing sources, each differing in size, depth, composition, and cooling/crystallization histories. Similar multiple degassing sources are common at explosive volcanoes, with frequent ascent and intrusion of small magma batches. Our innovative method permits the identification of those magma batches, which contributes to the interpretation of unrest signals, forecasting and assessment of volcanic hazards
    Description: Published
    Description: 95-104
    Description: 2V. Struttura e sistema di alimentazione dei vulcani
    Description: 3V. Proprietà chimico-fisiche dei magmi e dei prodotti vulcanici
    Description: 4V. Processi pre-eruttivi
    Description: JCR Journal
    Keywords: magmatic degassing ; hydrothermal systems ; explosive volcanism ; isotopic inversion
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Type: article
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  • 9
    Publication Date: 2021-05-12
    Description: Ischia, a volcanic island located 18 miles SW of Naples (Southern Italy), is a densely populated active caldera that last erupted in AD 1302. Melt inclusions in phenocrysts of the Vateliero and Cava Nocelle shoshonite^latite eruptive products (6th to 4th centuries BC) constrain the structure and nature of the Ischia deep magmatic feeding system.Their geochemical characteristics make Ischia a natural borehole for probing the physico-chemical conditions of magma generation in mantle contaminated by slab-derived fluids or melts, largely dominated by CO2.Volatile concentrations in olivine-hosted melt inclusions require gas^melt equilibria at between 3 and 18 km depth. In agreement with what has already been demonstrated at the other neighboring Neapolitan volcanoes (Procida, Campi Flegrei caldera and Somma^Vesuvius volcanic complex), a major crystallization depth at 8^10 km has been identified.The analyzed melt inclusions provide clear evidence for CO2-dominated gas fluxing and consequent dehydration of magma batches stagnating at crustal discontinuities. Gas fluxing is further supported by selective enrichment in K owing to fluid-transfer during magma differentiation.This takes place under oxidized conditions (Fe3þ /Fe 0·3) that can be fixed by an equimolar proportion of divalent and trivalent iron in the melt if post-entrapment crystallization of the host olivine is discarded.The melt inclusion data, together with data from the literature for other Neapolitan volcanoes, show that magmatism and volcanism in the Neapolitan area, despite differences in composition and eruption dynamics, are closely linked to supercritical CO2-rich fluids. These fluids are produced by devolatilization of subducting terrigenous^pelagic metasediments and infiltrate the overlying mantle wedge, generate magmas and control their ascent up to eruption. Geochemical characteristics of Ischia and the other Neapolitan volcanoes reveal that the extent of fluid or melt contamination of the pre-subduction asthenospheric mantle wedge was similar among these volcanoes. However, differences in the isotopic compositions of the erupted magmas (more enriched in radiogenic Sr at Ischia, Campi Flegrei and Somma^Vesuvius with respect to Procida) and the amount of H2O in the plumbing system of these volcanoes (almost double at Ischia, Campi Flegrei and Somma^Vesuvius than at Procida) reflect the different flow-rates of deep slab-derived fluids or melts through the mantle wedge, which, in turn, control the amount of generated magma.The high bulk permeability of the lithosphere below Ischia, Campi Flegrei and Somma^Vesuvius, determined by the occurrence of intersecting NW^SE and NE^SW regional fault systems, favours fluid ascent and accumulation at crustal levels, with consequent larger magma production and storage than at Procida, located along the NE^SW system.
    Description: Published
    Description: 951-984
    Description: 2V. Struttura e sistema di alimentazione dei vulcani
    Description: 3V. Proprietà chimico-fisiche dei magmi e dei prodotti vulcanici
    Description: 4V. Processi pre-eruttivi
    Description: 6A. Geochimica per l'ambiente e geologia medica
    Description: JCR Journal
    Keywords: CO2-fluxing ; melt inclusions ; redox state ; trachybasalts
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Type: article
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  • 10
    Publication Date: 2021-02-12
    Description: We have carried out a detailed petrological investigation on products of the poorly understood Nisida eruption, one of the most recent volcanic events (~4 ka BP) at Campi Flegrei caldera. We present major oxide contents and Sr–Nd isotopic data determined on bulk rock, groundmass and separated phenocrysts, along with major and volatile elements (H2O Cl, S and CO2) content of clinopyroxene-hosted melt inclusions from pumice fragments representative of the eruption. We use these to elaborate the role of magmatic evolution processes and fluid transfer prior to, and during, the Nisida eruption.The results indicate that the eruption was triggered by the arrival of a volatile-rich, shoshonite–latite magma. This magma was similar in terms of Sr and Nd isotopes (87Sr/86Sr ~0.70730; 143Nd/144Nd ~0.51250) to the Astroni 6 magmatic component. We infer that emplacement of this magma triggered resurgence of the caldera floor, and fed a large part of the volcanic activity at Campi Flegrei caldera during the past 5 ka. The new data on the Nisida eruption and other recent eruptions at Campi Flegrei, together with published data, suggest that fractional crystallization, and potentially fluid transfer from deep to shallow depths may account for most of the chemical variability of the erupted melt. Additional processes, such as magma mingling/mixing, and/or entrapment of antecrysts into the magma prior to the Nisida eruption are required to explain the large isotopic variation displayed by the analyzed products. The Nisida eruption occurred in the eastern sector of the resurgent Campi Flegrei caldera. In this sector, presently affected by an extensional stress regime, previous studies suggest that a Nisida-like eruption would be likely if the level of activity in the caldera were to intensify. In an area with such structural conditions, the ascent of a volatilerich magma such as that which erupted at Nisida should generate geophysical and geochemical signals detectable by an efficient monitoring network. The results of this investigation should inform the study of other active calderas worldwide that are experiencing persistent unrest, such as Rabaul, Aira, Iwo-Jima, Santorini, Long Valley and Yellowstone.
    Description: Published
    Description: 109-124
    Description: 2V. Struttura e sistema di alimentazione dei vulcani
    Description: 3V. Proprietà chimico-fisiche dei magmi e dei prodotti vulcanici
    Description: 4V. Processi pre-eruttivi
    Description: 6A. Geochimica per l'ambiente e geologia medica
    Description: JCR Journal
    Keywords: Campi Flegrei ; Sr and Nd isotopes ; Magma chamber processes ; Melt inclusions ; Fluid transfer ; Volcanic unrest
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Type: article
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