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  • 1
    Publication Date: 2017-08-04
    Description: The kinetics of dolomite dissolution have been experimentally investigated under subsurface conditions characteristic of the Rotliegend gas fields in the NE of The Netherlands. Experiments were performed in closed, stirred, batch reactors at far from equilibrium conditions, with dolomite powders of different grain sizes. The experiments were repeated for all grain sizes at 25°C and an experiment was also conducted in deionized water. The rates were derived from the measured concentrations of Mg 2+ or Ca 2+ released from dolomite dissolution and were normalized by the surface area of the minerals at each time interval. Regression of the rates with the pH resulted in the kinetic rate constants of: log k 1 = –8.16 ± 0.06 at 25°C and log k 2 = –7.61 ± 0.05 at 100°C (300 – 350 μm), log k 3 = –7.88 ± 0.20 at 25°C, log k 4 = –7.45 at 100°C (75 – 100 μm), log k 5 = –6.62 ± 0.50 at 25°C and log k 6 = –5.96 ± 1 at 100°C (20 – 25 μm). The results obtained in this study indicate that in an acidic regime the dissolution of dolomite in brine is a factor of 2 faster than in deionized water. It was also shown that the dissolution rates, when normalized by surface area, increase with decreasing grain size.
    Print ISSN: 1354-0793
    Topics: Chemistry and Pharmacology , Geosciences
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  • 2
    Electronic Resource
    Electronic Resource
    Oxford [u.a.] : International Union of Crystallography (IUCr)
    Acta crystallographica 47 (1991), S. 1376-1378 
    ISSN: 1600-5759
    Source: Crystallography Journals Online : IUCR Backfile Archive 1948-2001
    Topics: Chemistry and Pharmacology , Geosciences , Physics
    Type of Medium: Electronic Resource
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  • 3
    Electronic Resource
    Electronic Resource
    Springer
    Marine geophysical researches 8 (1986), S. 175-186 
    ISSN: 1573-0581
    Source: Springer Online Journal Archives 1860-2000
    Topics: Geosciences , Physics
    Notes: Abstract A simple, low cost, deep-towed system for high-resolution reflection seismic profiling is described. It consists of a vertical array with two hydrophones having a separation of 2.2 m and rigidly mounted onto streamlined tow bodies. Improvement of the signal-to-noise ratio is attained by simple stacking of the hydrophone outputs after signal conditioning and travel time corrections. The suppression of side echoes and surface reflections is achieved by an analog procedure which in effect improves the directional characteristics of the array. A circuit for automatic gain control is included to enhance weak signals as well as to suppress ringing. Results in Kiel Bay and over the crest of the Jan Mayen Ridge (northern Atlantic) suggest that this simple vertical array may supplement air gun systems better than conventional, surface pinger-type equipment.
    Type of Medium: Electronic Resource
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  • 4
    Electronic Resource
    Electronic Resource
    Springer
    Marine geophysical researches 6 (1984), S. 433-446 
    ISSN: 1573-0581
    Source: Springer Online Journal Archives 1860-2000
    Topics: Geosciences , Physics
    Notes: Abstract The Techniques of the IFG Hamburg for the use and handling of chemical sources for seismic energy generation are described. The results of normal and dispersed charge shooting in marine and combined land/sea projects are presented and it is shown, that the introduction of a clock based shooting technique leads to more efficiency for dispersed charges. The increase of safety and the economizing of explosives are outlined.
    Type of Medium: Electronic Resource
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  • 5
    Electronic Resource
    Electronic Resource
    Springer
    Marine geophysical researches 19 (1997), S. 257-265 
    ISSN: 1573-0581
    Keywords: Shot-induced noise ; shot interval ; seismic refraction ; S/N ratio
    Source: Springer Online Journal Archives 1860-2000
    Topics: Geosciences , Physics
    Notes: Abstract Seismic noise induced by the seismic source during continuous profiling reduces the signal-to-noise ratio and hence the data quality. This noise is largely dependent on the shot interval. In this paper, the noise amplitude of refraction seismic records from a special experiment is analysed as a function of the shot interval. An empirical exponential relationship between mean peak noise amplitude and shot interval is deduced. By increasing the shot interval, the induced noise can be minimized on all successive records. This results in an improvement of the data, predominantly the signal-to-noise ratio. Because the seismic signal and the shot-induced noise have nearly the same spectra, the chance of improving the signal-to-noise ratio by stacking is significantly reduced.
    Type of Medium: Electronic Resource
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  • 6
    Electronic Resource
    Electronic Resource
    Springer
    Marine geophysical researches 20 (1998), S. 239-247 
    ISSN: 1573-0581
    Keywords: bottom shots ; implosive sources ; P-waves ; Scholte waves ; seismic velocities
    Source: Springer Online Journal Archives 1860-2000
    Topics: Geosciences , Physics
    Notes: Abstract Bottom shots have been used for a number of years in seismic studies on the ocean floor. Most experiments utilized explosives as the energy source, though researchers have recognized the usefulness of collapsing water voids to produce seismoacoustic signals. Implosive sources, however, suffered generally from a lack of control of source depth. We present a new experimental tool, called SEEBOSEIS, to carry out seismic experiments on the seafloor utilizing hollow glass spheres as controlled implosive sources. The source is a 10-inch BENTHOS float with penetrator. Inside the sphere we place a small explosive charge (two detonators) to destabilize the glass wall. The time of detonation is controlled by an external shooting device. Test measurements on the Ninetyeast Ridge, Indian Ocean, show that the implosive sources can be used in seismic refraction experiments to image the subbottom P-wave velocity structure in detail beyond that possible with traditional marine seismic techniques. Additionally, the implosions permit the efficient generation of dispersed Scholte waves, revealing upper crustal S-wave velocities. The frequency band of seismic energy ranges from less than 1 Hz for Scholte modes up to 1000 Hz for diving P-waves. Therefore, broadband recording units with sampling rates 〉2000 Hz are recommended to sample the entire wave field radiated by implosive sources.
    Type of Medium: Electronic Resource
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  • 7
    Electronic Resource
    Electronic Resource
    Springer
    Marine geophysical researches 4 (1979), S. 247-253 
    ISSN: 1573-0581
    Source: Springer Online Journal Archives 1860-2000
    Topics: Geosciences , Physics
    Notes: Abstract The ocean bottom seismograph (OBS) of the Institut für Geophysik, Hamburg (IfG) is designed for refraction seismic experiments and for recording microseismic noise. Hydrophone signals are recorded directly on a casette tape recorder with a band width of 3–60 Hz. Signals from three component 1 Hz seismometers are recorded on a 2nd casette tape recorder in FM for a frequency range of 0.1–1 Hz. A telemetering buoy at the surface is connected with the OBS by a polypropylene rope.
    Type of Medium: Electronic Resource
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