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  • 1
    ISSN: 1432-0894
    Source: Springer Online Journal Archives 1860-2000
    Topics: Geosciences , Physics
    Notes: Abstract The sensitivity of the atmospheric circulation to an increase in ocean surface roughness in the Southern Hemisphere storm track is investigated in a paired general circulation model experiment. Such a change in sea roughness could be induced by ocean waves generated by storms. Two extended permanent-July runs are made. One with standard sea surface roughness, the other with ten times as a large surface roughness over open sea poleward of 40° S. The regional increase in ocean surface roughness significantly modifies the tropospheric circulation in the Southern Hemisphere. The strongest effect is the reduction of tropospheric winds (by 2 m/s or 10%) above the area with increased roughness. The poleward eddy momentum flux is reduced in the upper troposphere and the meridional eddy sensible heat flux is reduced in the lower troposphere. Zonal mean and eddy kinetic energy are consistently reduced.
    Type of Medium: Electronic Resource
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  • 2
    ISSN: 0009-2940
    Keywords: (Hydroxymethyl)diorganylsilanes, esters of ; Rearrangement, thermally induced ; Kinetics ; DSC ; Calculations, ab initio ; Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Esters of (Hydroxymethyl)diorganylsilanes: Synthesis and Thermally Induced RearrangementTwenty silanes of the type R1R2Si(H)CH2OR3 (A) were synthesized [R1, R2 = Me, Ph, 1-naphthyl, PhCH2,Me3SiCH2; OR3 = OC(O)Me, OC(O)Ph, OC(O)CF3, OS(O)2CF3, OP(O)Ph2, OC(O)Cl] and studied for their thermal behaviour. The silanes A undergo a thermally induced rearrangement to give the corresponding silanes R1R2Si(OR3)Me (B). For compounds with OR3 = OC(O)Cl, an additional decarboxylation takes place to yield the chlorosilanes R1R2Si(Cl)Me. Except for the derivatives with OR3 = OC(O)Cl, the energetic (reaction enthalpy) and kinetic data (reaction order, frequency factor, enthalpy and entropy of activation) of these reactions were studied by means of differential scanning calorimetry (DSC). In addition, the kinetics of all reactions were investigated by 1H-NMR spectroscopy. The transition state of the rearrangement was investigated by an ab initio study based on the model compound H3SiCH2OC(O)H [→ MeH2SiOC(O)H]. The theoretical data and the experimentally obtained energetic and kinetic data are discussed in terms of mechanistic aspects of the rearrangement reaction A → B.
    Additional Material: 3 Tab.
    Type of Medium: Electronic Resource
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  • 3
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    PANGAEA
    In:  Supplement to: Ritschel, Christoph; Ulbrich, Uwe; Névir, Peter; Rust, Henning (2017): Precipitation extremes on multiple timescales - Bartlett-Lewis rectangular pulse model and intensity-duration-frequency curves. Hydrology and Earth System Sciences, 21(12), 6501-6517, https://doi.org/10.5194/hess-21-6501-2017
    Publication Date: 2023-01-13
    Description: For several hydrological modelling tasks, precipitation time-series with a high (i.e. sub-daily) resolution are indispensable. This data is, however, not always available and thus model simulations are used to compensate. A canonical class of stochastic models for sub-daily precipitation are Poisson-cluster processes, with the Bartlett-Lewis rectangular pulse model (BLRPM) as a prominent representative. The BLRPM has been shown to well reproduce certain characteristics found in observations. Our focus is on intensity-duration-frequency relationship (IDF), which are of particular interest in risk assessment. Based on a high resolution precipitation time-series (5-min) from Berlin-Dahlem, BLRPM parameters are estimated and IDF curves are obtained on the one hand directly from the observations and on the other hand from BLRPM simulations. Comparing the resulting IDF curves suggests that the BLRPM is able to reproduce main features of IDF statistics across several durations but cannot capture singular events (here an event of magnitude 5 times larger than the second larges event). Here, IDF curves are estimated based on a parametric model for the duration dependence of the scale parameter in the General Extreme Value distribution; this allows to obtain a consistent set of curves over all durations. We use the BLRPM to investigate the validity of this approach based on simulated long time series.
    Keywords: Berlin, Germany; Berlin-Dahlem_BotGarden; DATE/TIME; ORDINAL NUMBER; Precipitation; Tipping bucket; Weather station/meteorological observation; WST
    Type: Dataset
    Format: text/tab-separated-values, 113952 data points
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  • 4
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    PANGAEA
    In:  Supplement to: Kadow, Christopher; Illing, Sebastian; Kröner, Igor; Ulbrich, Uwe; Cubasch, Ulrich (2017): Decadal climate predictions improved by ocean ensemble dispersion filtering. Journal of Advances in Modeling Earth Systems, https://doi.org/10.1002/2016MS000787
    Publication Date: 2023-01-13
    Description: Decadal predictions by Earth system models aim to capture the state and phase of the climate several years in advance. Atmosphere-ocean interaction plays an important role for such climate forecasts. While short-term weather forecasts represent an initial value problem and long-term climate projections represent a boundary condition problem, the decadal climate prediction falls in-between these two timescales. In recent years, more precise initialization techniques of coupled Earth system models and increased ensemble sizes have improved decadal predictions. However, climate models in general start losing the initialized signal and its predictive skill from one forecast year to the next. Here we show that the climate prediction skill of an Earth system model can be improved by a shift of the ocean state towards the ensemble mean of its individual members at seasonal intervals. We found that this procedure, called ensemble dispersion filter, results in more accurate results than the standard decadal prediction. Global mean and regional temperature, precipitation, and winter cyclone predictions show an increased skill up to 5 years ahead. Furthermore, the novel technique outperforms predictions with larger ensembles and higher resolution. Our results demonstrate how decadal climate predictions benefit from ocean ensemble dispersion filtering towards the ensemble mean.
    Keywords: File content; File format; File name; File size; Uniform resource locator/link to file
    Type: Dataset
    Format: text/tab-separated-values, 20 data points
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  • 5
  • 6
    Publication Date: 2016-05-21
    Description: he Mediterranean storm track constitutes a well-defined branch of the North Hemisphere storm track and is characterised by small but intense features and frequent cyclogenesis. The goal of this study is to assess the level of consensus among cyclone detection and tracking methods (CDTMs), to identify robust features and to explore sources of disagreement. A set of 14 CDTMs has been applied for computing the climatology of cyclones crossing the Mediterranean region using the ERA-Interim dataset for the period 1979–2008 as common testbed. Results show large differences in actual cyclone numbers identified by different methods, but a good level of consensus on the interpretation of results regarding location, annual cycle and trends of cyclone tracks. Cyclogenesis areas such as the north-western Mediterranean, North Africa, north shore of the Levantine basin, as well as the seasonality of their maxima are robust features on which methods show a substantial agreement. Differences among methods are greatly reduced if cyclone numbers are transformed to a dimensionless index, which, in spite of disagreement on mean values and interannual variances of cyclone numbers, reveals a consensus on variability, sign and significance of trends. Further, excluding ‘weak’ and ‘slow’ cyclones from the computation of cyclone statistics improves the agreement among CDTMs. Results show significant negative trends of cyclone frequency in spring and positive trends in summer, whose contrasting effects compensate each other at annual scale, so that there is no significant long-term trend in total cyclone numbers in the Mediterranean basin in the 1979–2008 period. Keywords: Mediterranean region, cyclones, automatic tracking methods, tracks, cyclogenesis (Published: 20 May 2016) Citation: Tellus A 2016, 68, 29391, http://dx.doi.org/10.3402/tellusa.v68.29391
    Print ISSN: 0280-6495
    Electronic ISSN: 1600-0870
    Topics: Geography , Geosciences , Physics
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  • 7
    Publication Date: 2019-12-03
    Description: In the early 1980s, Germany started a new era of modern Antarctic research. The Alfred Wegener Institute Helmholtz Centre for Polar and Marine Research (AWI) was founded and important research platforms such as the German permanent station in Antarctica, today called Neumayer III, and the research icebreaker Polarstern were installed. The research primarily focused on the Atlantic sector of the Southern Ocean. In parallel, the German National Science Foundation (Deutsche Forschungsgemeinschaft DFG) started a Priority Program ‘Antarctic Research’ (since 2003 called SPP-1158) to foster and intensify the cooperation between scientists from different German universities and the AWI as well as other institutes involved in polar research. Here, we review the main findings in meteorology and oceanography of the last decade, funded by the priority program. The paper presents field observations and modelling efforts, extending from the stratosphere to the deep ocean. The research spans a large range of temporal and spatial scales, including the interaction of both climate components. In particular, radiative processes, the interaction of the changing ozone layer with large-scale atmospheric circulations, and changes in the sea ice cover are discussed. Climate and weather forecast models provide an insight into the water cycle and the climate change signals associated with synoptic cyclones. Investigations of the atmospheric boundary layer focus on the interaction between atmosphere, sea ice, and ocean in the vicinity of polynyas and leads. The chapters dedicated to polar oceanography review the interaction between the ocean and ice shelves with regard to the freshwater input and discuss the changes in water mass characteristics, ventilation and formation rates, crucial for the deepest limb of the global, climate relevant meridional overturning circulation. They also highlight the associated storage of anthropogenic carbon as well as the cycling of carbon, nutrients, and trace metals in the ocean with special emphasis on the Weddell Sea.
    Repository Name: EPIC Alfred Wegener Institut
    Type: Article , isiRev
    Format: application/pdf
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  • 8
    Publication Date: 2022-09-29
    Repository Name: EPIC Alfred Wegener Institut
    Type: Conference , notRev
    Format: application/pdf
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